1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

Base Information

Chemical Name:1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne
CAS No.:175874-93-8
Molecular Formula:C₃₀H₃₂OSe₂
Molecular Weight:566.503
Hs Code.:

Synonyms:1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

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Chemical Property of 1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

Chemical Property:

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Technology Process of 1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

There total 6 articles about 1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 106-95-6
allyl bromide

: 175874-92-7
1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>hex-1-yn-3-ol

: 175874-93-8
1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

Guidance literature:: With potassium hydroxide; In dimethyl sulfoxide; at 55 ℃; for 10h;
DOI:10.1002/hlca.19960790104

Reference yield:

: 6317-49-3
4-oxopimelate

: 175874-93-8
1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

Guidance literature:: Multi-step reaction with 7 steps

1: 86 percent / triethyl orthoformate, TsOH / 10 h / 55 °C

2: 90 percent / LiAlH₄ / diethyl ether / 2 h

3: 100 percent / triethylamine / CH₂Cl₂ / 1 h / 0 °C

4: 1.) MeLi / 1.) 15 min, ether, 0 deg C; 2.) 1 h, ether, 0 deg C

5: 100 percent / TsOH / acetone / 12 h / 25 °C

6: 1.) BuLi / 1.) THF, 10 min, -78 deg C; 2.) THF, 70 min, -78 deg C

7: 81 percent / KOH / dimethylsulfoxide / 10 h / 55 °C

With potassium hydroxide; lithium aluminium tetrahydride; n-butyllithium; methyllithium; toluene-4-sulfonic acid; triethylamine; orthoformic acid triethyl ester; In diethyl ether; dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1002/hlca.19960790104

Reference yield:

: 19719-88-1
ethyl 3-<2-<2-(ethoxycarbonyl)ethyl><1,3>dioxolan-2-yl>propionate

: 175874-93-8
1-phenyl-6-(phenylselanyl)-3-<3-(phenylselanyl)propyl>-3-<(prop-2-en-1-yl)oxy>hex-1-yne

Guidance literature:: Multi-step reaction with 6 steps

1: 90 percent / LiAlH₄ / diethyl ether / 2 h

2: 100 percent / triethylamine / CH₂Cl₂ / 1 h / 0 °C

3: 1.) MeLi / 1.) 15 min, ether, 0 deg C; 2.) 1 h, ether, 0 deg C

4: 100 percent / TsOH / acetone / 12 h / 25 °C

5: 1.) BuLi / 1.) THF, 10 min, -78 deg C; 2.) THF, 70 min, -78 deg C

6: 81 percent / KOH / dimethylsulfoxide / 10 h / 55 °C

With potassium hydroxide; lithium aluminium tetrahydride; n-butyllithium; methyllithium; toluene-4-sulfonic acid; triethylamine; In diethyl ether; dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1002/hlca.19960790104