(1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

Base Information

Chemical Name:(1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate
CAS No.:1170682-06-0
Molecular Formula:C₁₆H₁₆ClNO₄
Molecular Weight:321.76
Hs Code.:

Synonyms:(1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

Suppliers and Price of (1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

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Chemical Property of (1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

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Technology Process of (1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

There total 1 articles about (1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 49678-54-8
methyl (E)-2-cyano-3-(4-chlorophenyl)-2-propenoate

: 111-30-8,29257-65-6,79215-57-9
Glutaraldehyde

: 1170682-06-0
(1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

: 1170682-07-1
(1S,2R,3R,6S)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

Guidance literature:: With (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; In chloroform; water; at 45 ℃; for 2h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tetlet.2009.02.209

Reference yield: 85.0%

: 1170682-06-0
(1S,2R,3R,6R)-methyl 2-(4-chlorophenyl)-1-cyano-3-formyl-6-hydroxycyclohexanecarboxylate

: 1170682-14-0
(1R,2R,3S,4R)-2-(4-chlorophenyl)-3-cyano-4-hydroxy-3-(methoxycarbonyl)cyclohexanecarboxylic acid

Guidance literature:: With sodium chlorite; potassium dihydrogenphosphate; 2-Methyl-1-butene; In water; tert-butyl alcohol;
DOI:10.1016/j.tetlet.2009.02.209