(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

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Chemical Name:(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol
CAS No.:1366497-78-0
Molecular Formula:C₂₆H₃₃N₃O₇Se
Molecular Weight:578.524
Hs Code.:

(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

Synonyms:(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

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Chemical Property of (2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

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Technology Process of (2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

There total 5 articles about (2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 67816-34-6
C₂₄H₃₈O₁₀Se₂

: 1366497-74-6
((2R,3S,6S)-3-hydroxy-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-3,6-dihydro-2H-pyran-2-yl)methyl methanesulfonate

: 1366497-78-0
(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

Guidance literature:: C₂₄H₃₈O₁₀Se₂; With sodium tetrahydroborate; In ethanol; Inert atmosphere;

((2R,3S,6S)-3-hydroxy-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-3,6-dihydro-2H-pyran-2-yl)methyl methanesulfonate; In tetrahydrofuran; ethanol; at 75 ℃; Inert atmosphere;
DOI:10.1016/j.tetlet.2012.01.102

Reference yield:

: 1366497-60-0
(2R,3S,6S)-6-(1-benzyl-1H-1,2,3-triazol-4-yl)-2-(hydroxymethyl)-3,6-dihydro-2H-pyran-3-ol

: 1366497-78-0
(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: pyridine / dichloromethane / 12 h / -20 - 20 °C / Inert atmosphere

2.1: sodium tetrahydroborate / ethanol / Inert atmosphere

2.2: 75 °C / Inert atmosphere

With pyridine; sodium tetrahydroborate; In ethanol; dichloromethane;
DOI:10.1016/j.tetlet.2012.01.102

Reference yield:

: 115029-76-0
((2R,3S,6S)-3-acetoxy-6-((trimethylsilyl)ethynyl)-3,6-dihydro-2H-pyran-2-yl)methyl acetate

: 1366497-78-0
(2S,3S,6S)-6-(1-phenyl-1H-1,2,3-triazol-4-yl)-2-((((3aR,5S,5aR,8aS,8bR)-2,2,7,7-tetramethyltetrahydro-3ah-bis[1,3]dioxolo[4,5-b:4',5'-d]pyran-5-yl)methylselanyl)methyl)-3,6-dihydro-2H-pyran-3-ol

Guidance literature:: Multi-step reaction with 4 steps

1.1: copper(l) iodide; tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Sonication; Inert atmosphere

2.1: water; potassium carbonate / methanol / 20 °C / Inert atmosphere

3.1: pyridine / dichloromethane / 12 h / -20 - 20 °C / Inert atmosphere

4.1: sodium tetrahydroborate / ethanol / Inert atmosphere

4.2: 75 °C / Inert atmosphere

With pyridine; sodium tetrahydroborate; copper(l) iodide; tetrabutyl ammonium fluoride; water; potassium carbonate; In tetrahydrofuran; methanol; ethanol; dichloromethane;
DOI:10.1016/j.tetlet.2012.01.102