[HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II)

Base Information

• Chemical Name: [HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II)
• CAS No.: 676264-72-5
• Molecular Formula: C₅₈H₈₂I₂Mn₂N₄
• Molecular Weight: 1199
• Mol file: 676264-72-5.mol

Synonyms:[HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II)

Chemical Property of [HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II)

There total 2 articles about [HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[(CH(CH3)2)2C6H3NCCH3]2CHMnIC4H8O (727427-53-4) → [HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II) (676264-72-5)

Guidance literature:

In toluene; refluxed in toluene for 0.5 h; evapd.(vac.), elem. anal.;

DOI:10.1002/ejic.200300289

Reference yield:

HC(CMeN-2,6-i-Pr2C6H3)2K (205993-24-4) → [HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II) (676264-72-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: toluene

In tetrahydrofuran; toluene;

DOI:10.1002/ejic.200300289

Reference yield: 65.0%

[HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-iodo)dimanganese(II) (676264-72-5) + phenyllithium (591-51-5) → [Mn(CH(C(CH3)N-2,6-(i-Pr)2C6H3)2)(Ph)] (676264-74-7)

Guidance literature:

In toluene; at low temperature; excess PhLi was used; recrystd. from pentane several times; elem. anal.;

DOI:10.1021/om030645i

upstream raw materials:

[(CH(CH₃)2)2C₆H₃NCCH₃]2CHMnIC₄H₈O

HC(CMeN-2,6-i-Pr₂C₆H₃)2K

Downstream raw materials:

manganese

[HC(CMeN(2,6-diisopropylphenyl))2]dimanganese(I)

[Mn(CH(C(CH₃)N-2,6-(i-Pr)2C₆H₃)2)(Ph)]

[HC(CMeN(2,6-diisopropylphenyl))2]bis(μ-oxo)dimanganese(III)