methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate

Base Information

• Chemical Name: methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate
• CAS No.: 115066-01-8
• Molecular Formula: C₁₇H₃₂O₄S
• Molecular Weight: 332.505
• Mol file: 115066-01-8.mol

Synonyms:methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate

Chemical Property of methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate

There total 1 articles about methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2S,3S)-3-propyl-2-oxiranemethanol (89321-71-1) → methyl-5,9-dihydroxy-8-butanethiol-6-dodecenoate (115066-01-8)

Guidance literature:

Multi-step reaction with 4 steps

1: 76 percent / pyridinium dichromate / CH₂Cl₂ / 14 h / Ambient temperature

2: 1.) 1N NaOH / 1.) CHCl₃, 5 min, 2.) toluene, 36 h, room temperature

3: 80 percent / NaBH₄ / methanol / 1 h / 0 - 20 °C

4: 100 percent / triethylamine / methanol / 45 h / Ambient temperature

With sodium hydroxide; sodium tetrahydroborate; dipyridinium dichromate; triethylamine; In methanol; dichloromethane;

DOI:10.1016/S0040-4020(01)90300-X

upstream raw materials:

(2S,3S)-3-propyl-2-oxiranemethanol

Refernces