[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

Base Information

Chemical Name:[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene
CAS No.:447462-40-0
Molecular Formula:C₂₂H₄₂O₂Si₂
Molecular Weight:394.745
Hs Code.:

[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-1-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

Synonyms:[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

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Chemical Property of [3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

Chemical Property:

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Technology Process of [3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

There total 16 articles about [3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 447462-36-4
{4-[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-phenyl}-dimethyl-amine

: 447462-40-0
[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

Guidance literature:: {4-[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-phenyl}-dimethyl-amine; With methyl iodide; for 10h;

With ammonia; sodium; In tetrahydrofuran; at -78 ℃; for 0.5h; Further stages.;
DOI:10.1021/ja025981p

Reference yield: 61.0%

: 447463-03-8
1-{4-[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-phenyl}-pyrrolidine

: 447462-40-0
[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

Guidance literature:: 1-{4-[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-phenyl}-pyrrolidine; With methyl iodide; for 48h;

With ammonia; sodium; In tetrahydrofuran; at -78 ℃; for 0.5h; Further stages.;
DOI:10.1021/ja025981p

Reference yield:

: 4096-21-3
N-phenylpyrrolidine

: 447462-40-0
[3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl]-benzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: 97 percent / (2S,5S)-5-benzyl-2-tert-butyl-3-methyl-imidazolidinone; HCl / CHCl₃; dioxane / 8 h / -20 °C

2.1: 98 percent / LiAlH₄ / tetrahydrofuran; diethyl ether / 0.08 h

3.1: 86 percent / triethylamine / CH₂Cl₂ / 7.5 h

4.1: MeI / 48 h

4.2: 61 percent / Na; NH₃ / tetrahydrofuran / 0.5 h / -78 °C

With hydrogenchloride; lithium aluminium tetrahydride; (2S,5S)-5-benzyl-2-tert-butyl-3-methyl-imidazolidinone; triethylamine; methyl iodide; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; chloroform;
DOI:10.1021/ja025981p