(1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

Base Information

Chemical Name:(1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran
CAS No.:861902-78-5
Molecular Formula:C₂₈H₃₀O₄
Molecular Weight:430.544
Hs Code.:

Synonyms:(1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

Suppliers and Price of (1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

Chemical Property:

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Technology Process of (1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

There total 5 articles about (1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 861902-77-4
(1'S,2R,3R,4R,5R)-3,4-(dimethanesulfonyloxy)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyltetrahydrofuran

: 861902-78-5
(1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

Guidance literature:: With sodium iodide; zinc; In N,N-dimethyl-formamide; at 140 ℃; for 34h;
DOI:10.1016/j.tet.2005.04.059

Reference yield:

: 861902-76-3
(1'S,2R,3R,4R,5R)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyltetrahydrofuran-3,4-diol

: 861902-78-5
(1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

Guidance literature:: Multi-step reaction with 2 steps

1: 74 percent / triethylamine / CH₂Cl₂ / 12 h / 0 - 20 °C

2: 89 percent / zinc; sodium iodide / dimethylformamide / 34 h / 140 °C

With triethylamine; sodium iodide; zinc; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2005.04.059

Reference yield:

: 861902-74-1
(1S,2'R,3'R,4'R,5'R)-1-[3',4'-bis(tert-butyldimethylsilanyloxy)-5'-trityloxymethyltetrahydrofuran-2'-yl]ethanol

: 861902-78-5
(1'S,2S,5S)-2-(1'-methoxymethoxyethyl)-5-trityloxymethyl-2,5-dihydrofuran

Guidance literature:: Multi-step reaction with 4 steps

1: 384 mg / N,N-diisopropylethylamine / CH₂Cl₂ / 48 h / 0 - 20 °C

2: 214 mg / n-tetrabutylammonium fluoride / tetrahydrofuran / 5 h / 20 °C

3: 74 percent / triethylamine / CH₂Cl₂ / 12 h / 0 - 20 °C

4: 89 percent / zinc; sodium iodide / dimethylformamide / 34 h / 140 °C

With tetrabutyl ammonium fluoride; triethylamine; N-ethyl-N,N-diisopropylamine; sodium iodide; zinc; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2005.04.059