Ir(2,2′:6′,2″-terpyridine)³⁺

Base Information

• Chemical Name: Ir(2,2′:6′,2″-terpyridine)³⁺
• CAS No.: 126614-54-8
• Molecular Formula: C₃₀H₂₂IrN₆
• Molecular Weight: 658.765
• Mol file: 126614-54-8.mol

Synonyms:Ir(2,2′:6′,2″-terpyridine)³⁺

Chemical Property of Ir(2,2′:6′,2″-terpyridine)³⁺

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Ir(2,2′:6′,2″-terpyridine)³⁺

There total 2 articles about Ir(2,2′:6′,2″-terpyridine)³⁺ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

potassium hexafluorophosphate (17084-13-8) + [Ir(2,2':6',2''-terpyridine)(4'-(4-bromophenyl)-2,2':6',2''-terpyridine)](PF6)3 + 4-cyanophenylboronic acid (126747-14-6) → Ir(2,2′:6′,2″-terpyridine)3+ (126614-54-8) + [Ir(2,2':6',2''-terpyridine)((NC5H4)2C5H2N(C6H4)2CN)](PF6)3

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; dimethyl sulfoxide; a Schlenk tube charged with Ir complex, PhB(OH)2, Na2CO3 in min. H2O, and DMSO, degassed, Pd complex added under N2, heated at 80°C for 2h; anion exchanged with KPF6, chromd. (alumina, hexane/EtOAc, then CH3CN/H2O), chromd. (alumina, CH3CN to CH3CN/H2O/KNO3), treated with KPF6;

DOI:10.1039/b313638h

Reference yield: 26.0%

potassium hexafluorophosphate (17084-13-8) + [Ir(2,2':6',2''-terpyridine)(4'-(4-bromophenyl)-2,2':6',2''-terpyridine)](PF6)3 + 4-(dimethylamino)benzene-boronic acid (28611-39-4) → Ir(2,2′:6′,2″-terpyridine)3+ (126614-54-8) + [Ir((NC5H4)2C5H2N(C6H4)2NMe2)2](3+) + [Ir(2,2':6',2''-terpyridine)((NC5H4)2C5H2N(C6H4)2NMe2)](PF6)3

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; dimethyl sulfoxide; a Schlenk tube charged with Ir complex, p-Me2NC6H4B(OH)2, Na2CO3 in min.H2O, and DMSO, degassed, Pd complex added under N2, heated at 85.degree .C for 12 h; anion exchanged with KPF6, chromd. (alumina, CH3CN to CH3CN/H2O), chromd. (alumina, CH3CN/acetone to CH3CN/acetone/H2O/KNO3), concd., treated with KPF6;

DOI:10.1039/b313638h

upstream raw materials:

potassium hexafluorophosphate

4-(dimethylamino)benzene-boronic acid

4-cyanophenylboronic acid