1-phenylphosphepane sulfide

Base Information

• Chemical Name: 1-phenylphosphepane sulfide
• CAS No.: 4963-97-7
• Molecular Formula: C₁₂H₁₇PS
• Molecular Weight: 224.307
• Mol file: 4963-97-7.mol

Synonyms:1-phenylphosphepane sulfide

Chemical Property of 1-phenylphosphepane sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenylphosphepane sulfide

There total 7 articles about 1-phenylphosphepane sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

(6-chlorohexyl)(methyl)phenylphosphine sulfide → cyclohexylmethylphenylphosphine sulfide (41899-39-2,73634-12-5) + 1-phenylphosphepane sulfide (4963-97-7)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 65 ℃; for 21h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.joc.7b01767

Reference yield:

1-phenylphosphepane (4963-96-6) → 1-phenylphosphepane sulfide (4963-97-7)

Guidance literature:

With sulfur; In benzene;

DOI:10.1039/j39660000245

Reference yield:

hex-5-enyl-phenyl-phosphane (4963-87-5) → 1-phenylphosphepane sulfide (4963-97-7)

Guidance literature:

Multi-step reaction with 2 steps

1: light petroleum / Irradiation

2: sulfur / benzene

With sulfur; In Petroleum ether; benzene;

DOI:10.1039/j39660000245

upstream raw materials:

1-phenylphosphepane

hex-5-enyl-phenyl-phosphane

Dichlorophenylphosphine

dimethylphenylphosphine sulfide