methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate

Base Information

• Chemical Name: methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate
• CAS No.: 102632-85-9
• Molecular Formula: C₁₉H₂₆O₄
• Molecular Weight: 318.413
• Mol file: 102632-85-9.mol

Synonyms:methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate

Chemical Property of methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate

There total 1 articles about methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

(2E,6E)-10-Hydroxy-2,6-dimethyl-10-phenyl-deca-2,6-dienoic acid methyl ester (102632-71-3) → methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate (102632-85-9)

Guidance literature:

With tetrafluoroboric acid; thallium(III) acetate; In acetone; for 1h;

DOI:10.1021/jo00364a035

Reference yield: 96.0%

methyl (6RS)-6-hydroxy-2-methyl-6-<(2SR,5SR)-5-phenyl-2-tetrahydrofuranyl>-2(E)-heptenoate (102632-85-9) → methyl-2,3-epoxy-6-hydroxy-2-methyl-6-(5-phenyl-2-tetrahydrofyranyl)heptanoate (102632-79-1,102681-33-4)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 23 ℃; for 4h;

DOI:10.1021/jo00364a035

upstream raw materials:

(2E,6E)-10-Hydroxy-2,6-dimethyl-10-phenyl-deca-2,6-dienoic acid methyl ester

Downstream raw materials:

methyl-2,3-epoxy-6-hydroxy-2-methyl-6-(5-phenyl-2-tetrahydrofyranyl)heptanoate