[1-(2′-(S)PPh2)-o-carborane]

Base Information

Chemical Name:[1-(2′-(S)PPh2)-o-carborane]
CAS No.:1334999-47-1
Molecular Formula:C₁₄H₂₁B₁₀PS
Molecular Weight:360.471
Hs Code.:

Synonyms:[1-(2′-(S)PPh2)-o-carborane]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [1-(2′-(S)PPh2)-o-carborane]

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Technology Process of [1-(2′-(S)PPh2)-o-carborane]

There total 2 articles about [1-(2′-(S)PPh2)-o-carborane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 10544-50-0
sulfur

: 36988-93-9
1-(diphenylphosphino)-o-carborane

: 1334999-47-1
[1-(2′-(S)PPh2)-o-carborane]

Guidance literature:: With Et₃N; In tetrahydrofuran; std. Schlenk technique; S8 (1 equiv.) and Et3N were added to soln. of B compd. in THF; stirred under reflu for 2 h; cooled to room temp.; chromd. (EtOAc/petroleum ether, 1/3);
DOI:10.1021/om200516b

Reference yield: 81.0%

: 36988-93-9
1-(diphenylphosphino)-o-carborane

: 7704-34-9
sulfur

: 1334999-47-1
[1-(2′-(S)PPh2)-o-carborane]

Guidance literature:: With Et₃N; In toluene; (N2); std. Schlenk technique; S was added to soln. of B compd. in toluene at room temp.; Et3N was added; stirred at 80°C for 12 h; evapd. (vac.); chromd. (silica gel, petroleum ether/CH2Cl2, 8/1); elem. anal.;
DOI:10.1021/om200528q

Reference yield: 85.0%

: 1334999-47-1
[1-(2′-(S)PPh2)-o-carborane]

: 7704-34-9
sulfur

: 1334999-50-6
1-SH-2-SPPh₂-1,2-closo-C₂B₁₀H₁₀

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; (N2); std. Schlenk technique; soln. of BuLi in hexane was added to soln.of B compd. in THF; stirred at 0°C for 0.5 h and at room temp. f or 1 h; S was added; stirred for 2 h; few drops of H2O added; evapd. (vac.); chromd. (silica gel, CH2Cl2); elem. anal.;
DOI:10.1021/om200528q