tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

Base Information

Chemical Name:tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside
CAS No.:860011-75-2
Molecular Formula:C₂₇H₃₇N₃O₇Si
Molecular Weight:543.692
Hs Code.:

Synonyms:tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

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Chemical Property of tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

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Technology Process of tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

There total 4 articles about tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 860011-74-1
tert-butyldimethylsilyl-2-azido-3-O-benzoyl-2-deoxy-4,6-O-(4-methoxybenzylidene)-β-D-glucopyranoside

: 860011-75-2
tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

Guidance literature:: With 4 A molecular sieve; sodium cyanoborohydride; trifluoroacetic acid; In N,N-dimethyl-formamide; at 0 ℃; for 2h;
DOI:10.1016/j.tetlet.2005.04.088

Reference yield:

: tert-butyldimethylsilyl-2-azido-2-deoxy-4,6-O-(4-methoxybenzylidene)-β-D-glucopyranoside

: 860011-75-2
tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: DMAP / pyridine / 20 °C

2: 97 percent / sodium cyanoborohydride; 4 Angstroem molecular sieves; trifluoroacetic acid / dimethylformamide / 2 h / 0 °C

With dmap; 4 A molecular sieve; sodium cyanoborohydride; trifluoroacetic acid; In pyridine; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2005.04.088

Reference yield:

: 99049-67-9
tert-Butyldimethylsilyl-2-azido-2-desoxy-β-D-glucopyranosid

: 860011-75-2
tert-butyldimethylsilyl 2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: p-toluenesulfonic acid / dimethylformamide / 0.5 h / 40 °C

2: DMAP / pyridine / 20 °C

3: 97 percent / sodium cyanoborohydride; 4 Angstroem molecular sieves; trifluoroacetic acid / dimethylformamide / 2 h / 0 °C

With dmap; 4 A molecular sieve; sodium cyanoborohydride; toluene-4-sulfonic acid; trifluoroacetic acid; In pyridine; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2005.04.088