1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

Base Information

Chemical Name:1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one
CAS No.:1439353-83-9
Molecular Formula:C₂₄H₃₅NO₂Si
Molecular Weight:397.633
Hs Code.:

Synonyms:1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

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Chemical Property of 1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

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Technology Process of 1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

There total 3 articles about 1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1439352-04-1
1-(4-((4-(benzylamino)-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

: 1439353-83-9
1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

Guidance literature:: With 5%-palladium/activated carbon; In ethanol; at 20 ℃; for 12h;
DOI:10.1016/j.bmc.2013.01.060

Reference yield:

: 1439349-08-2
4-((4-(3,3-dimethyl-2-oxobutoxy)-3-methylphenyl)diethylsilyl)-2-methylphenyl trifluoromethanesulfonate

: 1439353-83-9
1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 6 h / 100 °C / Inert atmosphere

2: 5%-palladium/activated carbon / ethanol / 12 h / 20 °C

With 5%-palladium/activated carbon; palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In ethanol; toluene; 1: |Buchwald-Hartwig Coupling;
DOI:10.1016/j.bmc.2013.01.060

Reference yield:

: 1247016-21-2
1-(4-(diethyl(4-hydroxy-3-methylphenyl)silyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

: 1439353-83-9
1-(4-((4-amino-3-methylphenyl)diethylsilyl)-2-methylphenoxy)-3,3-dimethylbutan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 1 h / 0 - 20 °C

2: palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 6 h / 100 °C / Inert atmosphere

3: 5%-palladium/activated carbon / ethanol / 12 h / 20 °C

With 5%-palladium/activated carbon; palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; triethylamine; In ethanol; dichloromethane; toluene; 2: |Buchwald-Hartwig Coupling;
DOI:10.1016/j.bmc.2013.01.060