2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

Base Information

Chemical Name:2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline
CAS No.:780757-50-8
Molecular Formula:C₃₃H₂₅BrN₂O
Molecular Weight:545.478
Hs Code.:

2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-<i>m</i>-tolyl-[1,10]phenanthroline

Synonyms:2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

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Chemical Property of 2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

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Technology Process of 2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

There total 5 articles about 2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 780757-49-5
{4-[3-(9-m-tolyl-[1,10]phenanthrolin-2-yl)-benzyloxy]-phenyl}-methanol

: 780757-50-8
2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

Guidance literature:: With phosphorus tribromide; In dichloromethane; at 0 - 23 ℃; for 12h;
DOI:10.1002/poc.790

Reference yield:

: 66-71-7
1,10-Phenanthroline

: 780757-50-8
2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 4 steps

1.1: tBuLi / tetrahydrofuran / 40 h / -78 - 23 °C

1.2: 75 percent / MnO₂ / CH₂Cl₂ / 24 h / 23 °C

2.1: 33 percent / NBS / CCl₄ / 2 h / Heating

3.1: 96 percent / CsCO₃ / acetonitrile / 72 h / 60 °C

4.1: 75 percent / PBr₃ / CH₂Cl₂ / 12 h / 0 - 23 °C

With N-Bromosuccinimide; tert.-butyl lithium; phosphorus tribromide; In tetrahydrofuran; tetrachloromethane; dichloromethane; acetonitrile;
DOI:10.1002/poc.790

Reference yield:

: 591-17-3
meta-bromotoluene

: 780757-50-8
2-[3-(4-bromomethyl-phenoxymethyl)-phenyl]-9-m-tolyl-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 4 steps

1.1: tBuLi / tetrahydrofuran / 40 h / -78 - 23 °C

1.2: 75 percent / MnO₂ / CH₂Cl₂ / 24 h / 23 °C

2.1: 33 percent / NBS / CCl₄ / 2 h / Heating

3.1: 96 percent / CsCO₃ / acetonitrile / 72 h / 60 °C

4.1: 75 percent / PBr₃ / CH₂Cl₂ / 12 h / 0 - 23 °C

With N-Bromosuccinimide; tert.-butyl lithium; phosphorus tribromide; In tetrahydrofuran; tetrachloromethane; dichloromethane; acetonitrile;
DOI:10.1002/poc.790