1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

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Chemical Name:1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene
CAS No.:153165-87-8
Molecular Formula:C₂₇H₂₅N₃O₄
Molecular Weight:455.513
Hs Code.:

Synonyms:1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

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Chemical Property of 1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

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Technology Process of 1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

There total 4 articles about 1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 153165-83-4
1R-(1β,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-2-cyclohexen-1-ol

: 65-85-0,8013-63-6
benzoic acid

: 153165-87-8
1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1016/S0040-4020(01)87223-9

Reference yield:

: 95308-53-5
4R-(4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-2-cyclohexen-1-one

: 153165-87-8
1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / NaBH₄, CeCl₃*7H₂O / methanol / 0.75 h

2: 70 percent / PPh₃, DEAD / tetrahydrofuran / 2 h / Ambient temperature

With sodium tetrahydroborate; cerium(III) chloride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol;
DOI:10.1016/S0040-4020(01)87223-9

Reference yield:

: 95308-48-8
2S-(2β,3β,4α,5α) 4-azido-5-hydroxy-2,3-bis(phenylmethoxy)-cyclohexanone

: 153165-87-8
1S-(1α,4α,5β,6β) 4-azido-5,6-bis(phenylmethoxy)-1-benzoyl-2-cyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1: 72 percent / mesyl chloride, pyridine / CH₂Cl₂ / 10 h / Ambient temperature

2: 78 percent / NaBH₄, CeCl₃*7H₂O / methanol / 0.75 h

3: 70 percent / PPh₃, DEAD / tetrahydrofuran / 2 h / Ambient temperature

With pyridine; sodium tetrahydroborate; cerium(III) chloride; methanesulfonyl chloride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4020(01)87223-9