(S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Base Information

Chemical Name:(S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol
CAS No.:151597-63-6
Molecular Formula:C₁₉H₃₂NO₈PSe
Molecular Weight:512.399
Hs Code.:

Synonyms:(S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Suppliers and Price of (S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

There total 5 articles about (S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 35717-98-7
bis(2-propyl)-p-toluenesulfonyloxymethylphosphonate

: 151597-63-6
(S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) NaH / 1.) THF, reflux, 5 h, 2.) THF, a) 0 deg C, 30 min, b) RT, 14 h

2: TsOH / methanol / 8 h / 60 °C

3: 98 percent / diisopropylethylamine / CH₂Cl₂ / 14 h / Ambient temperature

4: 98 percent / cyclohexene / Pd(OH)2/C / ethanol / 6 h / Heating

5: n-Bu₃P / tetrahydrofuran / 24.5 h / 0 - 20 °C

With tributylphosphine; sodium hydride; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; cyclohexene; palladium dihydroxide; In tetrahydrofuran; methanol; ethanol; dichloromethane;
DOI:10.1021/jm00071a003

Reference yield:

: 151223-13-1
(S)-4-O-benzyl-2-O-<(diisopropylphosphono)methyl>-1,2,4-butanetriol

: 151597-63-6
(S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / diisopropylethylamine / CH₂Cl₂ / 14 h / Ambient temperature

2: 98 percent / cyclohexene / Pd(OH)2/C / ethanol / 6 h / Heating

3: n-Bu₃P / tetrahydrofuran / 24.5 h / 0 - 20 °C

With tributylphosphine; N-ethyl-N,N-diisopropylamine; cyclohexene; palladium dihydroxide; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1021/jm00071a003

Reference yield:

: 151223-14-2
(S)-4-O-benzyl-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-1,2,4-butanetriol

: 151597-63-6
(S)-2-O-<(diisopropylphosphono)methyl>-1-O-(methoxymethyl)-4-O-<(2-nitrophenyl)selenyl>-1,2,4-butanetriol

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / cyclohexene / Pd(OH)2/C / ethanol / 6 h / Heating

2: n-Bu₃P / tetrahydrofuran / 24.5 h / 0 - 20 °C

With tributylphosphine; cyclohexene; palladium dihydroxide; In tetrahydrofuran; ethanol;
DOI:10.1021/jm00071a003