C₅H₄S₄C₃HS₂S(CH₂CH₂O)5CH₂CH₂OC₆Cl₃O₂

Base Information

• Chemical Name: C₅H₄S₄C₃HS₂S(CH₂CH₂O)5CH₂CH₂OC₆Cl₃O₂
• CAS No.: 943302-63-4
• Molecular Formula: C₂₆H₂₉Cl₃O₈S₇
• Molecular Weight: 800.332
• Mol file: 943302-63-4.mol

Synonyms:C₅H₄S₄C₃HS₂S(CH₂CH₂O)5CH₂CH₂OC₆Cl₃O₂

Chemical Property of C₅H₄S₄C₃HS₂S(CH₂CH₂O)5CH₂CH₂OC₆Cl₃O₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅H₄S₄C₃HS₂S(CH₂CH₂O)5CH₂CH₂OC₆Cl₃O₂

There total 3 articles about C₅H₄S₄C₃HS₂S(CH₂CH₂O)5CH₂CH₂OC₆Cl₃O₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

C20H30O6S7 (943302-70-3) + chloranil (118-75-2) → C5H4S4C3HS2S(CH2CH2O)5CH2CH2OC6Cl3O2 (943302-63-4)

Guidance literature:

C₂₀H₃₀O₆S₇; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.333333h;

chloranil; In tetrahydrofuran; at 20 ℃; Further stages.;

DOI:10.1021/ja0702824

Reference yield:

toluene-4-sulfonic acid 2-[2-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethyl ester (42749-28-0) → C5H4S4C3HS2S(CH2CH2O)5CH2CH2OC6Cl3O2 (943302-63-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: CsOH*H₂O / tetrahydrofuran / 0.5 h / 20 °C

1.2: 83 percent / tetrahydrofuran / 20 °C

2.1: NaH / tetrahydrofuran / 0.33 h / 20 °C

2.2: 44 percent / tetrahydrofuran / 20 °C

With cesium hydroxide; sodium hydride; In tetrahydrofuran;

DOI:10.1021/ja0702824

Reference yield:

4-(2-cyanoethylthio)-4',5'-(ethylenedithio)tetrathiafulvalene (503302-37-2) → C5H4S4C3HS2S(CH2CH2O)5CH2CH2OC6Cl3O2 (943302-63-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: CsOH*H₂O / tetrahydrofuran / 0.5 h / 20 °C

1.2: 83 percent / tetrahydrofuran / 20 °C

2.1: NaH / tetrahydrofuran / 0.33 h / 20 °C

2.2: 44 percent / tetrahydrofuran / 20 °C

With cesium hydroxide; sodium hydride; In tetrahydrofuran;

DOI:10.1021/ja0702824

upstream raw materials:

C₂₀H₃₀O₆S₇

chloranil

toluene-4-sulfonic acid 2-[2-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethyl ester

4-(2-cyanoethylthio)-4',5'-(ethylenedithio)tetrathiafulvalene