[Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl]

Base Information

• Chemical Name: [Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl]
• CAS No.: 1377829-43-0
• Molecular Formula: C₅₃H₅₃ClO₁₂Si₈Ti
• Molecular Weight: 1190.01
• Mol file: 1377829-43-0.mol

Synonyms:[Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl]

Chemical Property of [Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl]

There total 1 articles about [Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

1,3,5,7,9,11,14-heptaphenyltricyclo[7.3.3.1(5,11)]heptasiloxane-endo-3,7,14-triol (444315-26-8) + (1-(chlorodimethylsilyl)-2,3,4,5-tetramethylcyclopentadienyl)titanium trichloride (443889-16-5) → [Ti(η5-C5Me4SiMe2OPh7Si7O11-κ2O2)Cl] (1377829-43-0)

Guidance literature:

With N(C₂H₅)3; In dichloromethane; byproducts: N(C2H5)3HCl; (Ar, Schlenk) a soln. of N(C2H5)3 in CH2Cl2 was added to the mixt. of Ti-complex and siloxane, stirring for 12 h; the solid was filtered, volatiles were removed under vac., extd. with hexane (3x), concd., cooled at -20°C; elem. anal.;

DOI:10.1021/ic300583g

upstream raw materials:

1,3,5,7,9,11,14-heptaphenyltricyclo[7.3.3.1(5,11)]heptasiloxane-endo-3,7,14-triol

(1-(chlorodimethylsilyl)-2,3,4,5-tetramethylcyclopentadienyl)titanium trichloride