3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester

Base Information

Chemical Name:3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester
CAS No.:207788-86-1
Molecular Formula:C₁₃H₁₄N₂O₈
Molecular Weight:326.263
Hs Code.:

Synonyms:3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester

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Technology Process of 3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester

There total 2 articles about 3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 99-34-3
3,5-dinitrobenzoic acid

: methyl (3R)-3-hydroxy-2-methylbutanoate

: 207788-86-1
3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 48h; Ambient temperature;
DOI:10.1055/s-1998-2052

Reference yield:

: 3976-69-0
Methyl (R)-3-hydroxybutyrate

: 207788-86-1
3,5-Dinitro-benzoic acid (1S,2R)-2-methoxycarbonyl-1-methyl-propyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: LiCl, LDA, BuLi / tetrahydrofuran; hexane / 1.) -30 deg C, 4 h, 2.) -30 deg C, 1.5 d

2: 74 percent / Ph₃P, DEAD / tetrahydrofuran / 48 h / Ambient temperature

With n-butyllithium; triphenylphosphine; lithium chloride; lithium diisopropyl amide; diethylazodicarboxylate; In tetrahydrofuran; hexane;
DOI:10.1055/s-1998-2052