(1-ethoxyethyl)zirconocene chloride

Base Information

Chemical Name:(1-ethoxyethyl)zirconocene chloride
CAS No.:116052-40-5
Molecular Formula:C₁₄H₁₉ClOZr
Molecular Weight:329.981
Hs Code.:

Synonyms:(1-ethoxyethyl)zirconocene chloride

Suppliers and Price of (1-ethoxyethyl)zirconocene chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1-ethoxyethyl)zirconocene chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1-ethoxyethyl)zirconocene chloride

There total 1 articles about (1-ethoxyethyl)zirconocene chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 1291-32-3
zirconocene dichloride

: 116005-05-1
(1-ethoxyethyl)tri-n-butylstannane

: 116052-40-5
(1-ethoxyethyl)zirconocene chloride

: 1461-25-2
tetra-n-butyltin(IV)

Guidance literature:: With n-butyl lithium; In tetrahydrofuran; hexane; byproducts: LiCl; Sep. cooling (THF, -78°C) of Cp2ZrCl2 under Ar with stirring and of Sn-compd. Dropwise addn. of n-BuLi to stannane and after 10 min at -78°C rapid addn. of mixt. to Cp2ZrCl2 soln. Stirring (1 h, -78°C), warming (room temp.).; Evapn. of mixt. gives oil solidified on standing, washing (hexane) to remove Bu4Sn, extn. (C6H6), removal of LiCl by filtn., evapn., washing (hexane) and vac. drying. Elem. anal.;
DOI:10.1021/om00101a012

Reference yield: 70.0%

: 116052-40-5
(1-ethoxyethyl)zirconocene chloride

: 1291-32-3
zirconocene dichloride

: 11087-35-7
zirconocene diethoxide

: 11087-28-8
ethoxyzirconocene chloride

Guidance literature:: In ⁽²⁾H₈-toluene; Combining of toluene-d8 and starting compd. in an NMR tube and heating in an oil bath to ca. 145°C for 24 h (N2 or Ar).; React. monitored by NMR.;
DOI:10.1021/om00101a012