O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

Base Information

Chemical Name:O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat
CAS No.:120312-01-8
Molecular Formula:C₂₅H₂₇Cl₃N₄O₅
Molecular Weight:569.872
Hs Code.:

Synonyms:O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

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Chemical Property of O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

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Technology Process of O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

There total 7 articles about O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 120312-00-7
4-O-allyl-2-azido-3,6-di-O-benzyl-2-desoxy-D-glucopyranose

: 545-06-2
trichloroacetonitrile

: 120312-01-8
O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

Guidance literature:: In dichloromethane; for 12h; Ambient temperature;

Reference yield:

: 99049-68-0
tert-Butyldimethylsilyl-2-azido-2-desoxy-4,6-O-isopropyliden-β-D-glucopyranosid

: 120312-01-8
O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

Guidance literature:: Multi-step reaction with 6 steps

1: 68 percent / NaH / dimethylformamide / 1.5 h / Ambient temperature

2: 148 mg / 60percent CF₃COOH / CH₂Cl₂ / 1 h

3: 1.) (Bu₃Sn)2O; 2.) (NBu₄)I / 1.) toluene, heating, 2 h; 2.) 2 h

4: 83 percent / NaH / tetrahydrofuran / 3 h / Heating

5: 96 percent / 1M (Bu₄N)F, CH₃COOH / tetrahydrofuran / 12 h / Ambient temperature

6: 75 percent / CH₂Cl₂ / 12 h / Ambient temperature

With tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; sodium hydride; acetic acid; trifluoroacetic acid; bis(tri-n-butyltin)oxide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 120312-09-6
tert-Butyldimethylsilyl-2-azido-3,6-di-O-benzyl-2-desoxy-β-D-glucopyranosid

: 120312-01-8
O-(4-Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-α-D-glucopyranosyl)trichloracetimidat

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / NaH / tetrahydrofuran / 3 h / Heating

2: 96 percent / 1M (Bu₄N)F, CH₃COOH / tetrahydrofuran / 12 h / Ambient temperature

3: 75 percent / CH₂Cl₂ / 12 h / Ambient temperature

With tetrabutyl ammonium fluoride; sodium hydride; acetic acid; In tetrahydrofuran; dichloromethane;