bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾

Base Information

Chemical Name:bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾
CAS No.:95387-34-1
Molecular Formula:C₄HFeO₄*C₃₆H₃₀NP₂
Molecular Weight:708.477
Hs Code.:

bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate<sup>(0)</sup>

Synonyms:bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾

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Chemical Property of bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾

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Technology Process of bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾

There total 3 articles about bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 56791-54-9
bis(triphenylphosphine)iminium tetracarbonylhydridoferrate⁽⁰⁾

: 758-12-3
deuteroacetic acid

: 95387-34-1
bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾

Guidance literature:: In tetrahydrofuran; addn. of soln. of Fe-complex to CH3CO2D, stirring for 2.5 h; evapn. in vac., recrystn. (THF/hexane);
DOI:10.1021/ja00294a037

Reference yield:

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 95387-34-1
bis(triphenylphosphine)iminium tetracarbonyldeuterioferrate⁽⁰⁾

Guidance literature:: With deuteriated sodium hydroxide; In deuteromethanol; water-d2; NaOD (2.0 mL, 40% in D2O) and CH3OD (6.0 mL) syringed into Schlenk flask and stirred for 15 min, Fe(CO)5 (3.7 mmol) added under N2, stirred for 1 h, (PPN)Cl (3.6 mmol) added, followed by CH3OD, stirred 25 min; filtered, solid washed with CH3OD, dried in vac.;