methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside
• CAS No.: 57784-05-1
• Molecular Formula: C₃₄H₂₉BrO₁₁S
• Molecular Weight: 725.568
• Mol file: 57784-05-1.mol

Synonyms:methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside

Chemical Property of methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside

There total 3 articles about methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methyl 2,3,6-tri-O-benzoyl-α-D-glucopyranoside (57784-06-2,6344-46-3) + 4-bromobenzenesulfonyl chloride (98-58-8) → methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside (57784-05-1)

Guidance literature:

With pyridine; for 48h; Ambient temperature;

DOI:10.1021/jo00269a025

Reference yield:

1-benzoylimidazole (10364-94-0) + 4-bromobenzenesulfonyl chloride (98-58-8) + methyl-alpha-D-glucopyranoside (97-30-3) → methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside (57784-05-1)

Guidance literature:

With pyridine; Yield given. Multistep reaction; 1.) MeCN, reflux, 24 h, 2.) RT, 48 h;

DOI:10.1021/jo00269a025

Reference yield:

→ methyl 2,3,6-tri-O-benzoyl-4-O-<(4-bromophenyl)sulfonyl>-α-D-glucopyranoside (57784-05-1)

Guidance literature:

entspr. 4-Alkohol, Brosylchlorid;

DOI:10.1016/S0008-6215(00)84335-9

upstream raw materials:

methyl 2,3,6-tri-O-benzoyl-α-D-glucopyranoside

4-bromobenzenesulfonyl chloride

1-benzoylimidazole

methyl-alpha-D-glucopyranoside

Downstream raw materials:

methyl 2,3,6-tri-O-benzoyl-4-deoxy-4-thiocyano-α-D-galactopyranoside

methyl 4-S-acetyl-2,3,6-tri-O-benzoyl-4-thio-α-D-galactopyranoside

methyl 2,3,6-tri-O-benzoyl-4-thio-α-D-galactopyranoside