(m-CH₃-C₆H₄)5C₆₀H

Base Information

Chemical Name:(m-CH₃-C₆H₄)5C₆₀H
CAS No.:287491-40-1
Molecular Formula:C₉₅H₃₆
Molecular Weight:1177.33
Hs Code.:

(m-CH<sub>3</sub>-C<sub>6</sub>H<sub>4</sub>)5C<sub>60</sub>H

Synonyms:(m-CH₃-C₆H₄)5C₆₀H

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (m-CH₃-C₆H₄)5C₆₀H

Chemical Property:

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Technology Process of (m-CH₃-C₆H₄)5C₆₀H

There total 1 articles about (m-CH₃-C₆H₄)5C₆₀H which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 591-17-3
meta-bromotoluene

: 99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0
fullerene-C₆₀

: 287491-40-1
(m-CH₃-C₆H₄)5C₆₀H

Guidance literature:: meta-bromotoluene; With iodine; magnesium; In tetrahydrofuran; for 0.833333h; Reflux; Inert atmosphere;

With copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; at -78 ℃; for 0.25h; Inert atmosphere;

fullerene-C₆₀; In tetrahydrofuran; 1,2-dichloro-benzene; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/ja807627u

Reference yield: 63.0%

: 14221-02-4
tetrakis(triphenylphosphine)platinum

: 287491-40-1
(m-CH₃-C₆H₄)5C₆₀H

: [(η2-(m-CH3-C6H4)5C60H)Pt(P(C6H5)3)2]

Guidance literature:: In tetrahydrofuran; byproducts: P(C6H5)3; reaction carried out under highly purified nitrogen, three-necked flask fitted with a stirrer bar, a serum cap, and an N2 inlet tube charged with (m-CH3C6H4)5C60H and THF, Pt(PPh3)4 then added and the reaction mixture stirred at room temp. for 0.5 h; solvent removed under vacuum, residue chromatographed on an Al2O3 columnwith toluene/petroleum ether (3:2) as eluent, pink band collected, solv ent removed, elem. anal., mixture of isomers;

Reference yield: 51.0%

: 14221-01-3
tetrakis(triphenylphosphine) palladium⁽⁰⁾

: 287491-40-1
(m-CH₃-C₆H₄)5C₆₀H

: [(η2-(m-CH3-C6H4)5C60H)Pd(P(C6H5)3)2]

Guidance literature:: In tetrahydrofuran; byproducts: P(C6H5)3; reaction carried out under highly purified nitrogen, three-necked flask fitted with a stirrer bar, a serum cap, and an N2 inlet tube charged with (m-CH3C6H4)5C60H and THF, Pd(PPh3)4 then added and the reaction mixture stirred at room temp. for 0.5 h; solvent removed under vacuum, residue chromatographed on an Al2O3 columnwith toluene/petroleum ether (3:2) as eluent, pink band collected, solv ent removed, elem. anal., mixture of isomers;