(+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

Base Information

Chemical Name:(+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone
CAS No.:146830-54-8
Molecular Formula:C₃₀H₃₈O₃SSi
Molecular Weight:506.781
Hs Code.:

Synonyms:(+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

Suppliers and Price of (+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

Chemical Property:

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Technology Process of (+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

There total 3 articles about (+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 502-44-3,24980-41-4,80137-66-2
hexahydro-2H-oxepin-2-one

: 146830-54-8
(+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / methanol / Heating

2: 98 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

3: 1) lithium diisopropylamide / 1) THF, -78 deg C, 1 h, 2) -50 deg C

With 1H-imidazole; lithium diisopropyl amide; In methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo00060a038

Reference yield:

: 4547-43-7
methyl 6-hydroxycaproate

: 146830-54-8
(+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

2: 1) lithium diisopropylamide / 1) THF, -78 deg C, 1 h, 2) -50 deg C

With 1H-imidazole; lithium diisopropyl amide; In N,N-dimethyl-formamide;
DOI:10.1021/jo00060a038

Reference yield:

: 1519-39-7
(R)-methyl p-tolyl sulfoxide

: 146830-59-3
6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid methyl ester

: 146830-54-8
(+)(R)-1-(p-Tolylsulfinyl)-7-<(tert-butyldiphenylsilyl)oxy>-2-heptanone

Guidance literature:: With lithium diisopropyl amide; Yield given. Multistep reaction; 1) THF, -78 deg C, 1 h, 2) -50 deg C;
DOI:10.1021/jo00060a038