Mesitylcopper(I)

Base Information

• Chemical Name: Mesitylcopper(I)
• CAS No.: 75732-01-3
• Molecular Formula: C9H11 Cu
• Molecular Weight: 182.732
• European Community (EC) Number: 685-737-1
• Mol file: 75732-01-3.mol

Synonyms:MESITYLCOPPER(I);75732-01-3;Copper,(2,4,6-trimethylphenyl)-;mesitylcopper;(2,4,6-Trimethylphenyl)copper(I);MFCD00015622;copper(1+);1,3,5-trimethylbenzene-6-ide;mesityl copper;(2,4,6-TRIMETHYLPHENYL)COPPER;SY066979;CS-0111043;E76196

Chemical Property of Mesitylcopper(I)

Chemical Property:

• Melting Point: 184-191°C
• PSA: 0.00000
• LogP: 2.40950
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive, light sensitive,
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 182.015672
• Heavy Atom Count: 10
• Complexity: 185

Purity/Quality:

99% ^*data from raw suppliers

Mesitylcopper(I), min. 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=[C-]C(=C1)C)C.[Cu+]
• Uses: Starting material for a variety of copper(I) complexes. Mesitylcopper(I) is can be used to synthesize: Homo and heteroleptic copper(I) complexes such as Cu(I) alkoxides, siloxides, phosphates, amides, and phosphides.Biorelevant copper(I) complexes as biomimetic model compounds. Copper nanoparticles from stabilizing primary amines. It can also be used as a selective mesityl group transfer reagent in stoichiometric C?C and C?heteroatom bond-forming reactions. Mesitylcopper is an organometal used to synthesize compounds such as copper diketonate complexes.

Technology Process of Mesitylcopper(I)

There total 2 articles about Mesitylcopper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

copper(l) chloride + 2-mesitylmagnesium bromide (2633-66-1) → mesitylcopper(I) (75732-01-3)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/anie.201703923

Reference yield:

2,4,6-trimethylphenyl bromide (576-83-0) + copper(l) chloride → mesitylcopper(I) (75732-01-3)

Guidance literature:

2,4,6-trimethylphenyl bromide; With magnesium; In tetrahydrofuran; Reflux; Inert atmosphere;

copper(l) chloride; In tetrahydrofuran; at -78 - 20 ℃; for 25h; Inert atmosphere;

DOI:10.1021/ja4012113

Reference yield: 100.0%

morpholine (110-91-8,99108-56-2) + mesitylcopper(I) (75732-01-3) → C4H8NO(1-)*Cu(1+) (77590-49-9) + 1,3,5-trimethyl-benzene (108-67-8)

Guidance literature:

In tetrahydrofuran; THF, ambient temp., excess of amine;; evapd. or filtered; elem. anal.;;

DOI:10.1021/ic50222a071

upstream raw materials:

2-mesitylmagnesium bromide

2,4,6-trimethylphenyl bromide

Downstream raw materials:

diphenic acid dimethyl ester

2-mesitylbenzoic acid methyl ester

Mesityl 2-bromobenzoate

Mesityl 2-mesitylbenzoate

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