(Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal

Base Information

• Chemical Name: (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal
• CAS No.: 151105-95-2
• Molecular Formula: C₂₂H₁₉F₂NO
• Molecular Weight: 351.396

Synonyms:(Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal

Chemical Property of (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal

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Technology Process of (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal

There total 14 articles about (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenol → (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal (151105-95-2) + (E)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal (151105-94-1)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jm00075a021

Reference yield: 20.0%

(E)-3-[3-Bromo-4,5-bis-(4-fluoro-phenyl)-2-isopropyl-pyrrol-1-yl]-prop-2-en-1-ol → (E)-3-[3-Bromo-4,5-bis-(4-fluoro-phenyl)-2-isopropyl-pyrrol-1-yl]-propenal + (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal (151105-95-2)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jm00075a021

Reference yield: 20.0%

(E)-3-[2-(4-Fluoro-phenyl)-5-isopropyl-3-pyridin-2-yl-pyrrol-1-yl]-prop-2-en-1-ol → (E)-3-[2-(4-Fluoro-phenyl)-5-isopropyl-3-pyridin-2-yl-pyrrol-1-yl]-propenal + (Z)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal (151105-95-2)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/jm00075a021

upstream raw materials:

1-(4-fluorophenyl)-5-methyl-2-(2-pyridyl)-1,4-hexanedione

2-(4-fluorophenyl)-5-(1-methylethyl)-3-(2-pyridyl)-1H-pyrrole

4-[2-(4-Fluoro-phenyl)-5-isopropyl-1H-pyrrol-3-yl]-pyridine

2-(4-fluorophenyl)-5-(1-methylethyl)-3-(N-oxo-4-pyridyl)-1H-pyrrole

Downstream raw materials:

(E)-3-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-2-propenal

(+/-)-(E)-7-<2,3-bis(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-5-hydroxy-3-oxo-6-heptenoic acid methyl ester

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