2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

Base Information

Chemical Name:2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)
CAS No.:1188371-68-7
Molecular Formula:C₆₈H₇₅O₁₃PSi
Molecular Weight:1159.39
Hs Code.:

Synonyms:2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

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Chemical Property of 2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

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Technology Process of 2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

There total 6 articles about 2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1188371-65-4
2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol

: 108549-23-1
Dibenzyl N,N-diisopropylphosphoramidite

: 1188371-68-7
2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

Guidance literature:: 2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol; Dibenzyl N,N-diisopropylphosphoramidite; With 1H-tetrazole; In dichloromethane; acetonitrile; at 20 ℃; for 18h; Inert atmosphere;

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetonitrile; at -60 - 20 ℃;
DOI:10.1002/ejoc.200900476

Reference yield:

: C₆₈H₇₅O₁₂PSi

: 1188371-68-7
2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetonitrile; at -60 ℃; for 1h;
DOI:10.1016/j.chembiol.2011.07.022

Reference yield:

: 1188371-65-4
2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol

: 1188371-68-7
2,3,5,6-O-tetrakis(benzyloxymethyl)-1-O-(tert-butyldiphenylsilyl)-D-myo-insitol 4-(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-tetrazole / dichloromethane; acetonitrile / 18 h / 20 °C

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane; acetonitrile / 1 h / -60 °C

With 1H-tetrazole; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetonitrile;
DOI:10.1016/j.chembiol.2011.07.022