10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4:5,8-dimethanotriphenylene

Base Information

• Chemical Name: 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4:5,8-dimethanotriphenylene
• CAS No.: 67102-98-1
• Molecular Formula: C₂₀H₆Br₂Cl₁₂
• Molecular Weight: 831.512
• Mol file: 67102-98-1.mol

Synonyms:10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene

Chemical Property of 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4:5,8-dimethanotriphenylene

Chemical Property:

• Vapor Pressure: 1.09E-15mmHg at 25°C

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

2,3-DIBROMONAPHTHALENE-BIS(HEXACHLOROCYCLOPENTADIENE) ADDUCT 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4:5,8-dimethanotriphenylene

There total 3 articles about 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4:5,8-dimethanotriphenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

10-bromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene (80789-65-7) → 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene (67102-98-1)

Guidance literature:

With bromine; iron; In various solvent(s); for 2h; Heating;

DOI:10.1021/jo00162a013

Reference yield:

→ 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-(4ac,4bc,8ac,12bc)-1,4,4a,4b,5,8,8a,12b-octahydro-1r,4;5,8-dimethano-triphenylene (67102-98-1)

Guidance literature:

With bromine; iron; 1,1,2,2-tetrachloroethane;

DOI:10.1021/ja01652a083

Reference yield:

1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8dimethano-triphenylene (5696-92-4,147730-93-6) → 10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene (67102-98-1)

Guidance literature:

With bromine; In Trichloroethylene;

DOI:10.1002/ejoc.201403504

upstream raw materials:

10-bromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene

1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8dimethano-triphenylene

Downstream raw materials:

2,3-dibromonaphthalene

1,4-dihydro-1,4-epoxyanthracene

Tetracen

anthracene