[3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

Base Information

Chemical Name:[3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane
CAS No.:870137-66-9
Molecular Formula:C₂₄H₂₈O₂SSi
Molecular Weight:408.637
Hs Code.:

Synonyms:[3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

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Chemical Property of [3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

Chemical Property:

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Technology Process of [3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

There total 4 articles about [3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 870137-65-8
[5-(4-ethylphenyl)-2-thienyl]dimethylsilane

: 94-59-7
1-allyl-3,4-methylenedioxybenzene

: 870137-66-9
[3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

Guidance literature:: With dihydrogen hexachloroplatinate; In toluene; at 80 ℃; for 3.5h;
DOI:10.1002/ejoc.200500252

Reference yield:

: 168269-58-7
2-(4-vinylphenyl)thiophene

: 870137-66-9
[3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 87 percent / H₂ / 10 percent Pd-C / methanol / 15 h / 20 °C

2.1: nBuLi / tetrahydrofuran; hexane / 2 h / -50 °C

2.2: 78 percent / tetrahydrofuran; hexane / -50 - 0 °C

3.1: 16 percent / hexachloroplatinic acid / toluene / 3.5 h / 80 °C

With dihydrogen hexachloroplatinate; n-butyllithium; hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol; hexane; toluene;
DOI:10.1002/ejoc.200500252

Reference yield:

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 870137-66-9
[3-(benzo[1,3]dioxol-5-yl)propyl][5-(4-ethylphenyl)-2-thienyl]dimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1.1: TMEDA; nBuLi / tetrahydrofuran; hexane / 2 h / 20 °C

1.2: zinc chloride / tetrahydrofuran; hexane / 1 h / Heating

1.3: 73 percent / tetrakis(triphenylphosphane)palladium / tetrahydrofuran / 15 h / Heating

2.1: 87 percent / H₂ / 10 percent Pd-C / methanol / 15 h / 20 °C

3.1: nBuLi / tetrahydrofuran; hexane / 2 h / -50 °C

3.2: 78 percent / tetrahydrofuran; hexane / -50 - 0 °C

4.1: 16 percent / hexachloroplatinic acid / toluene / 3.5 h / 80 °C

With dihydrogen hexachloroplatinate; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol; hexane; toluene;
DOI:10.1002/ejoc.200500252