(+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

Base Information

Chemical Name:(+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane
CAS No.:141860-59-5
Molecular Formula:C₁₆H₁₆O₄
Molecular Weight:272.301
Hs Code.:

Synonyms:(+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

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Chemical Property of (+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

Chemical Property:

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Technology Process of (+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

There total 6 articles about (+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 141860-45-9
(+/-)-2-benzyloxymethyl-1,4-benzodioxan-6-carbaldehyde

: 141860-59-5
(+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

Guidance literature:: With potassium fluoride; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; Ambient temperature;

Reference yield:

: 4049-39-2
4-benzyloxy-3-hydroxy-benzaldehyde

: 141860-59-5
(+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

Guidance literature:: Multi-step reaction with 5 steps

1: 1) sodium hydride / 1) dimethyl formamide, r.t., 1 h, 2) 16 h

2: 90 percent / hydrogen / 5percent Pd/C / ethyl acetate / 2 h / 760 Torr / Ambient temperature

3: 77 percent / potassium carbonate, 18-crown-6 / acetonitrile / 16 h / Ambient temperature

4: 71 percent / sodium hydroxide, tetrabutylammonium hydrogen sulfate / H₂O; CH₂Cl₂ / 16 h / Ambient temperature

5: 80 percent / m-chloroperbenzoic acid, KF / CH₂Cl₂ / Ambient temperature

With potassium fluoride; sodium hydroxide; 18-crown-6 ether; hydrogen; tetra(n-butyl)ammonium hydrogensulfate; sodium hydride; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In dichloromethane; water; ethyl acetate; acetonitrile;

Reference yield:

: 141860-41-5
(+/-)-4-benzyloxy-3-<(2,3-epoxypropan-1-yl)oxy>benzaldehyde

: 141860-59-5
(+/-)-2-benzyloxymethyl-6-hydroxy-1,4-benzodioxane

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / hydrogen / 5percent Pd/C / ethyl acetate / 2 h / 760 Torr / Ambient temperature

2: 77 percent / potassium carbonate, 18-crown-6 / acetonitrile / 16 h / Ambient temperature

3: 71 percent / sodium hydroxide, tetrabutylammonium hydrogen sulfate / H₂O; CH₂Cl₂ / 16 h / Ambient temperature

4: 80 percent / m-chloroperbenzoic acid, KF / CH₂Cl₂ / Ambient temperature

With potassium fluoride; sodium hydroxide; 18-crown-6 ether; hydrogen; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In dichloromethane; water; ethyl acetate; acetonitrile;