(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

Base Information

Chemical Name:(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde
CAS No.:81312-41-6
Molecular Formula:C₁₇H₁₇F₃N₂O₇
Molecular Weight:418.326
Hs Code.:

Synonyms:(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

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Chemical Property of (2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

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Technology Process of (2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

There total 4 articles about (2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 81312-40-5
2-(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)ethanol

: 81312-41-6
(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -70 - -30 ℃; for 2.5h;
DOI:10.1016/S0008-6215(00)80669-2

Reference yield:

: 81312-36-9
ethyl 2-(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetate

: 81312-41-6
(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: diisobutylaluminium hydride / tetrahydrofuran / 0 degC, 3 h; methanol, 1.5 h, 23 degC

2: CH₂Cl₂ / 0 degC, 15 min; 23 degC, 4 h

3: 73 percent / oxalyl chloride, dimethyl sulfoxide / CH₂Cl₂ / 2.5 h / -70 - -30 °C

With oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0008-6215(00)80669-2

Reference yield:

: 4-Nitro-benzoic acid (2S,3S,4S,6R)-4-amino-6-(2-hydroxy-ethyl)-2-methyl-tetrahydro-pyran-3-yl ester

: 81312-41-6
(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)acetaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 0 degC, 15 min; 23 degC, 4 h

2: 73 percent / oxalyl chloride, dimethyl sulfoxide / CH₂Cl₂ / 2.5 h / -70 - -30 °C

With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane;
DOI:10.1016/S0008-6215(00)80669-2