methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Base Information

Chemical Name:methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate
CAS No.:402589-16-6
Molecular Formula:C₁₈H₁₉NO₇S
Molecular Weight:393.417
Hs Code.:

Synonyms:methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Suppliers and Price of methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

There total 4 articles about methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 463-71-8
thiophosgene

: methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α,β-D-ribo-hex-2-ulofuranosyl)onate amine

: 402589-16-6
methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

: methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-β-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Guidance literature:: With calcium carbonate; In chloroform; water; at 20 ℃; for 72h;
DOI:10.1016/S0040-4039(01)01845-7

Reference yield:

: 133886-01-8
2-azido-2-deoxy-6-O-benzyl-3,4-O-isopropylidene-β-D-psico-furanose

: 402589-16-6
methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Guidance literature:: Multi-step reaction with 4 steps

1: NaIO₄; RuCl₃*H₂O / 0.25 h / 20 °C

2: methanol; diethyl ether / 0.33 h / 0 °C

3: 95 percent / H₂ / Pd-C / 0.5 h / 20 °C

4: 65 percent / CaCO₃ / CHCl₃; H₂O / 72 h / 20 °C

With ruthenium trichloride; sodium periodate; hydrogen; calcium carbonate; palladium on activated charcoal; In methanol; diethyl ether; chloroform; water;
DOI:10.1016/S0040-4039(01)01845-7

Reference yield:

: (3aR,4S,6R,6aR)-4-Azido-6-benzoyloxymethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole-4-carboxylic acid

: 402589-16-6
methyl (6-O-benzoyl-2-deoxy-3,4-O-isopropylidene-α-D-ribo-hex-2-ulofuranosyl isothiocyanate)onate

Guidance literature:: Multi-step reaction with 3 steps

1: methanol; diethyl ether / 0.33 h / 0 °C

2: 95 percent / H₂ / Pd-C / 0.5 h / 20 °C

3: 65 percent / CaCO₃ / CHCl₃; H₂O / 72 h / 20 °C

With hydrogen; calcium carbonate; palladium on activated charcoal; In methanol; diethyl ether; chloroform; water;
DOI:10.1016/S0040-4039(01)01845-7