1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene

Base Information

• Chemical Name: 1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene
• CAS No.: 885324-87-8
• Molecular Formula: C₂₆H₁₉F₃O₃S
• Molecular Weight: 468.496
• Mol file: 885324-87-8.mol

Synonyms:1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene

Chemical Property of 1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene

There total 1 articles about 1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

trifluoromethylsulfonic anhydride (358-23-6) + 4-tritylphenol (978-86-9) → 1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene (885324-87-8)

Guidance literature:

With triethylamine; In dichloromethane; for 0.5h; cooling;

DOI:10.1039/b516804j

Reference yield: 90.0%

1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene (885324-87-8) + 2-methyl-but-3-yn-2-ol (115-19-5) → 4-(3-hydroxy-3-methylbutyn-1-yl)tetraphenylmethane (444278-90-4)

Guidance literature:

With copper(l) iodide; triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 20 ℃; for 24h;

DOI:10.1039/b516804j

Reference yield: 40.0%

1-trifluoromethylsulfonyloxy-4-triphenylmethylbenzene (885324-87-8) + 4,6-diphenyl-2-[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,1': 2',1-terphenyl-3-yl]-1,3,5-triazine → 2,4-diphenyl-6-[4-triphenylmethyl-1,1':5',1'':2'',1'''-quaterphenyl-3'-yl]-1,3,5-triazine

Guidance literature:

With palladium diacetate; potassium carbonate; XPhos; In tetrahydrofuran; water; for 24h; Inert atmosphere; Reflux;

upstream raw materials:

trifluoromethylsulfonic anhydride

4-tritylphenol

Downstream raw materials:

4-(3-hydroxy-3-methylbutyn-1-yl)tetraphenylmethane

3',5'-O-(tetraisopropyldisiloxane-1,3-diyl)-5-[4-(triphenylmethyl)phenylethynyl]-2'-deoxyuridine

((4-ethynylphenyl)methanetriyl)tribenzene