C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

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Chemical Name:C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆
CAS No.:74540-78-6
Molecular Formula:C₃₀H₂₆NOPRe*F₆P
Molecular Weight:778.687
Hs Code.:

C<sub>5</sub>H<sub>5</sub>Re(NO)CHC<sub>6</sub>H<sub>5</sub>P(C<sub>6</sub>H<sub>5</sub>)3<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>=Re(C<sub>5</sub>H<sub>5</sub>)NOP(C<sub>6</sub>H<sub>5</sub>)3CHC<sub>6</sub>H<sub>5</sub>PF<sub>6</sub>

Synonyms:C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

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Chemical Property of C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

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Technology Process of C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

There total 2 articles about C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (η(5)-cyclopentadienyl)Re(NO)(P(C6H5)3)(benzyl)

: 437-17-2
tritylium hexafluorophosphate

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

Guidance literature:: In dichloromethane; soln. of Re-complex in CH2Cl2 was cooled to -78°C, ligand was added, soln. was stirred at -78°C for 30 min, allowed to warm to room temp. under N2, after 2 h hexane was added, solvents were removed under vac.; solid was washed with hexane and ether, recrystd. from CH2Cl2/hexane (freezer);
DOI:10.1021/ja00382a021

Reference yield:

: (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5)

: (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5)

: 437-17-2
tritylium hexafluorophosphate

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

Guidance literature:: In dichloromethane-d2; byproducts: Ph3COCH3; soln. of mixt. of Re-complexes in CD2Cl2 was cooled to -78°C, ligand in CD2Cl2, tube was quickly transferred to -70°C NMR probe; monitored by NMR;
DOI:10.1021/ja00382a021

Reference yield: 80.0%

: lithium triethyl borodeuteride

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 82399-52-8
C₅H₅Re(NO)CH⁽²⁾HC₆H₅P(C₆H₅)3

Guidance literature:: In tetrahydrofuran; dichloromethane; Re-complex was dissolved in CH2Cl2, cooled to -78°C, ligand in THF was added dropwise under N2, after 15 min at -78°C soln. was allowed to warm to room temp., solvent was removed under vac.; residue extd. with benzene, filtered through silica gel, benzene was removed, recrystd. from CH2Cl2/hexane;
DOI:10.1021/ja00382a021