methyl 27-deoxy-27-oxookadaate

Base Information

• Chemical Name: methyl 27-deoxy-27-oxookadaate
• CAS No.: 1616799-64-4
• Molecular Formula: C₄₅H₆₈O₁₃
• Molecular Weight: 817.027
• Mol file: 1616799-64-4.mol

Synonyms:methyl 27-deoxy-27-oxookadaate

Chemical Property of methyl 27-deoxy-27-oxookadaate

Chemical Property:

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Technology Process of methyl 27-deoxy-27-oxookadaate

There total 1 articles about methyl 27-deoxy-27-oxookadaate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

okadaic acid (78111-17-8) → methyl 27-deoxy-27-oxookadaate (1616799-64-4)

Guidance literature:

Multi-step reaction with 4 steps

1: benzene; methanol; hexane / 0.33 h / 20 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 2 h / 0 - 20 °C

3: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 7 h / 20 °C / Inert atmosphere

4: hydrogen fluoride / acetonitrile / 0.75 h / 20 °C

With 1H-imidazole; hydrogen fluoride; sodium hydrogencarbonate; Dess-Martin periodane; In methanol; hexane; dichloromethane; N,N-dimethyl-formamide; acetonitrile; benzene;

DOI:10.1021/ja501795c

upstream raw materials:

okadaic acid

Refernces