C₃₉H₅₁F₃O₁₀SSi

Base Information

Chemical Name:C₃₉H₅₁F₃O₁₀SSi
CAS No.:615285-13-7
Molecular Formula:C₃₉H₅₁F₃O₁₀SSi
Molecular Weight:796.975
Hs Code.:

C<sub>39</sub>H<sub>51</sub>F<sub>3</sub>O<sub>10</sub>SSi

Synonyms:C₃₉H₅₁F₃O₁₀SSi

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Chemical Property of C₃₉H₅₁F₃O₁₀SSi

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Technology Process of C₃₉H₅₁F₃O₁₀SSi

There total 23 articles about C₃₉H₅₁F₃O₁₀SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 145100-51-2
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide

: 615284-86-1
C₃₈H₅₂O₈Si

: 615285-13-7
C₃₉H₅₁F₃O₁₀SSi

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; toluene; at -78 ℃; for 1h;
DOI:10.1002/anie.200351825

Reference yield:

: 392663-00-2
(E)-(S)-6-Benzyloxy-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-5-methyl-hex-3-en-2-one

: 615285-13-7
C₃₉H₅₁F₃O₁₀SSi

Guidance literature:: Multi-step reaction with 21 steps

1.1: 98 percent / LiI; LiAlH₄ / diethyl ether / -100 - 0 °C

2.1: 97 percent / AcOH / H₂O / 5 h / 40 °C

3.1: 70 percent / NaHCO₃; N-iodosuccinimide / tetrahydrofuran / 36 h / 0 °C

4.1: 99 percent / Et₃N; 4-(dimethylamino)pyridine / CH₂Cl₂ / 10 h / 25 °C

5.1: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

6.1: 99 percent / H₂; Raney-Ni catalyst / ethanol / 1 h / 25 °C

7.1: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

8.1: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 0 - 25 °C

9.1: Mg / tetrahydrofuran / 2 h / 25 °C

9.2: tetrahydrofuran / 2 h / -78 - 0 °C

10.1: 95 percent / Dess-Martin periodinane / CH₂Cl₂ / 4 h / 0 - 25 °C

11.1: 98 percent / triethyl orthoformate; p-TsOH / 2.5 h / 55 °C

12.1: N-methylmorpholine-N-oxide; OsO₄ / tetrahydrofuran; H₂O; 2-methyl-propan-2-ol / 14 h / 25 °C

12.2: 100 percent / NaIO₄; aq. saline solution buffer / tetrahydrofuran; 2-methyl-propan-2-ol / 5 h / 25 °C

13.1: n-BuLi / tetrahydrofuran; toluene / 3 h / -30 °C

13.2: tetrahydrofuran / 1 h / -30 °C

14.1: 13.2 g / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 2 h / 0 °C

15.1: 85 percent / TMSOTf / CH₂Cl₂ / 3 h / -78 - -30 °C

16.1: 95 percent / pyridine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 3 h / 25 °C

17.1: 91 percent / 2,6-lutidine; N-bromosuccinimide / acetonitrile; H₂O / 2 h / 25 °C

18.1: 92 percent / NaBH₄ / methanol / 0.08 h / -5 °C

19.1: 56 percent / trifluoroacetic acid / CH₂Cl₂ / 3 h / 0 °C

20.1: 80 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2 h / -78 - 0 °C

21.1: 83 percent / potassium bis(trimethylsilyl)amide / tetrahydrofuran; toluene / 1 h / -78 °C

With pyridine; 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; N-Bromosuccinimide; N-iodo-succinimide; osmium(VIII) oxide; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; trimethylsilyl trifluoromethanesulfonate; Raney-Ni catalyst; hydrogen; potassium hexamethylsilazane; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; magnesium; acetic acid; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; orthoformic acid triethyl ester; trifluoroacetic acid; lithium iodide; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 20.1: Swern oxidation;
DOI:10.1021/ja0547477

Reference yield:

: 392663-05-7
(2R,3S,5R)-2-((1S,2R)-3-Benzyloxy-1-iodo-2-methyl-propyl)-5-hydroxymethyl-tetrahydro-furan-3-ol

: 615285-13-7
C₃₉H₅₁F₃O₁₀SSi

Guidance literature:: Multi-step reaction with 18 steps

1.1: 99 percent / Et₃N; 4-(dimethylamino)pyridine / CH₂Cl₂ / 10 h / 25 °C

2.1: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

3.1: 99 percent / H₂; Raney-Ni catalyst / ethanol / 1 h / 25 °C

4.1: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

5.1: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 0 - 25 °C

6.1: Mg / tetrahydrofuran / 2 h / 25 °C

6.2: tetrahydrofuran / 2 h / -78 - 0 °C

7.1: 95 percent / Dess-Martin periodinane / CH₂Cl₂ / 4 h / 0 - 25 °C

8.1: 98 percent / triethyl orthoformate; p-TsOH / 2.5 h / 55 °C

9.1: N-methylmorpholine-N-oxide; OsO₄ / tetrahydrofuran; H₂O; 2-methyl-propan-2-ol / 14 h / 25 °C

9.2: 100 percent / NaIO₄; aq. saline solution buffer / tetrahydrofuran; 2-methyl-propan-2-ol / 5 h / 25 °C

10.1: n-BuLi / tetrahydrofuran; toluene / 3 h / -30 °C

10.2: tetrahydrofuran / 1 h / -30 °C

11.1: 13.2 g / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 2 h / 0 °C

12.1: 85 percent / TMSOTf / CH₂Cl₂ / 3 h / -78 - -30 °C

13.1: 95 percent / pyridine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 3 h / 25 °C

14.1: 91 percent / 2,6-lutidine; N-bromosuccinimide / acetonitrile; H₂O / 2 h / 25 °C

15.1: 92 percent / NaBH₄ / methanol / 0.08 h / -5 °C

16.1: 56 percent / trifluoroacetic acid / CH₂Cl₂ / 3 h / 0 °C

17.1: 80 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2 h / -78 - 0 °C

18.1: 83 percent / potassium bis(trimethylsilyl)amide / tetrahydrofuran; toluene / 1 h / -78 °C

With pyridine; 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; N-Bromosuccinimide; osmium(VIII) oxide; n-butyllithium; oxalyl dichloride; trimethylsilyl trifluoromethanesulfonate; Raney-Ni catalyst; hydrogen; potassium hexamethylsilazane; Dess-Martin periodane; toluene-4-sulfonic acid; magnesium; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; orthoformic acid triethyl ester; trifluoroacetic acid; palladium dihydroxide; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 17.1: Swern oxidation;
DOI:10.1021/ja0547477