Technology Process of C79H113NO11Si
There total 17 articles about C79H113NO11Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 7.7 g / Et3N / CH2Cl2 / 20 °C
2: n-BuLi; BF3*Et2O / tetrahydrofuran; diethyl ether / 5.5 h / -95 - -78 °C
With
n-butyllithium; boron trifluoride diethyl etherate; triethylamine;
In
tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol061582d
- Guidance literature:
-
Multi-step reaction with 6 steps
1: H2 / Pd/C / methanol
2: SO3*pyridine; DMSO; (i-Pr)2NEt / CH2Cl2 / 0.5 h / 20 °C
3: 2.05 g / K2CO3 / 2 h / 20 °C
4: LiOH; H2O / tetrahydrofuran / 13 h / 0 - 20 °C
5: 7.7 g / Et3N / CH2Cl2 / 20 °C
6: n-BuLi; BF3*Et2O / tetrahydrofuran; diethyl ether / 5.5 h / -95 - -78 °C
With
lithium hydroxide; n-butyllithium; pyridine-SO3 complex; boron trifluoride diethyl etherate; water; hydrogen; potassium carbonate; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1021/ol061582d
- Guidance literature:
-
Multi-step reaction with 8 steps
1: SO3*pyridine; DMSO; (i-Pr)2NEt / CH2Cl2 / 0.5 h / 20 °C
2: 4.96 g / CHCl3 / 24 h / 20 °C
3: H2 / Pd/C / methanol
4: SO3*pyridine; DMSO; (i-Pr)2NEt / CH2Cl2 / 0.5 h / 20 °C
5: 2.05 g / K2CO3 / 2 h / 20 °C
6: LiOH; H2O / tetrahydrofuran / 13 h / 0 - 20 °C
7: 7.7 g / Et3N / CH2Cl2 / 20 °C
8: n-BuLi; BF3*Et2O / tetrahydrofuran; diethyl ether / 5.5 h / -95 - -78 °C
With
lithium hydroxide; n-butyllithium; pyridine-SO3 complex; boron trifluoride diethyl etherate; water; hydrogen; potassium carbonate; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform;
DOI:10.1021/ol061582d