2,4-diallyloxyphenol

Base Information

• Chemical Name: 2,4-diallyloxyphenol
• CAS No.: 1416159-14-2
• Molecular Formula: C₁₂H₁₄O₃
• Molecular Weight: 206.241
• Mol file: 1416159-14-2.mol

Synonyms:2,4-diallyloxyphenol

Chemical Property of 2,4-diallyloxyphenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2,4-diallyloxyphenol

There total 1 articles about 2,4-diallyloxyphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,4-Bis(allyloxy)benzaldehyde (96601-10-4) → 2,4-diallyloxyphenol (1416159-14-2)

Guidance literature:

With potassium hydrogensulfate; water; dihydrogen peroxide; In methanol; at 23 ℃; Inert atmosphere;

DOI:10.1039/c2cc36861g

Reference yield:

(2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-(4-(bromomethyl)phenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate (1261966-06-6) + 2,4-diallyloxyphenol (1416159-14-2) → (2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-(4-((2,4-bis(allyloxy)phenoxy)methyl)phenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate (1416159-11-9)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; potassium carbonate; In acetone; at 70 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c2cc36861g

Reference yield:

2,4-diallyloxyphenol (1416159-14-2) → (2S,3R,4S,5R,6R)-2-(4-((2,4-dihydroxyphenoxy)methyl)phenoxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol (1416159-06-2)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium carbonate; tetra-(n-butyl)ammonium iodide / acetone / 24 h / 70 °C / Inert atmosphere

2: sodium methylate / dichloromethane; methanol / 3 h / 23 °C / Inert atmosphere

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; zinc(II) chloride; tri-n-butyl-tin hydride / tetrahydrofuran; N,N-dimethyl-formamide / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tri-n-butyl-tin hydride; sodium methylate; tetra-(n-butyl)ammonium iodide; potassium carbonate; zinc(II) chloride; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetone;

DOI:10.1039/c2cc36861g

upstream raw materials:

2,4-Bis(allyloxy)benzaldehyde

Downstream raw materials:

(2S,3R,4S,5R,6R)-2-(4-((2,4-bis(allyloxy)phenoxy)methyl)phenoxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

(2S,3R,4S,5R,6R)-2-(4-((2,4-dihydroxyphenoxy)methyl)phenoxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

(2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-(4-((2,4-bis(allyloxy)phenoxy)methyl)phenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate