OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

Base Information

Chemical Name:OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2
CAS No.:249630-71-5
Molecular Formula:C₂₄H₅₄ClNOOsP₂
Molecular Weight:660.299
Hs Code.:

Synonyms:OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

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Chemical Property of OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

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Technology Process of OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

There total 4 articles about OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 100-64-1
cyclohexanone-oxime

: ((C₃H₇)3P)2OsH₂Cl₂

: 249630-71-5
OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

Guidance literature:: With Et₃N; In not given; Os complex treated at room temp. under Ar with a stoich. amt. of the oxime in the presence of 5 equiv. of Et3N; detected by (31)P NMR spectrum;
DOI:10.1021/om000208t

Reference yield: 82.0%

: 100-64-1
cyclohexanone-oxime

: 183624-80-8,156129-27-0,159992-38-8,131296-70-3
bis(triisopropylphosphane)(dihydrido)dichloroosmium(IV)

: 249630-71-5
OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

Guidance literature:: With Et₃N; In toluene; byproducts: Et3NHCl; exclusion of air; equimolar amt. of oxime, 5 equivs. of Et3N, stirring for 20 min at room temp.; filtration, evapn., washing (MeOH), drying (vac.); elem. anal.;
DOI:10.1021/om9904192

Reference yield: 20.0%

: 100-64-1
cyclohexanone-oxime

: ((C₃H₇)3P)2OsH₂Cl₂

: 288324-67-4
[OsHCl₂(P(CH(CH₃)2)3)2NC(CH₂)4CH₂]

: 249630-71-5
OsH2Cl(κN,κO-[ON=C(CH2)4CH2])(P(i)Pr3)2

Guidance literature:: In toluene; brown soln. of Os complex treated with imine under Ar at room temp. for1 h; concd., MeOH added, brown solid isolated; detected by (31)P NMR spectrum;
DOI:10.1021/om000208t