C₄₈H₇₇NO₉Si

Base Information

Chemical Name:C₄₈H₇₇NO₉Si
CAS No.:1402167-46-7
Molecular Formula:C₄₈H₇₇NO₉Si
Molecular Weight:840.226
Hs Code.:

C<sub>48</sub>H<sub>77</sub>NO<sub>9</sub>Si

Synonyms:C₄₈H₇₇NO₉Si

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Chemical Property of C₄₈H₇₇NO₉Si

Chemical Property:

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Technology Process of C₄₈H₇₇NO₉Si

There total 25 articles about C₄₈H₇₇NO₉Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1402167-45-6
(2E,4Z,6S,7R,8E,10S,11R,12S,14R)-methyl 11-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-15-(2',5'-diisopropoxy-6'-methoxy-3'-nitrophenyl)-6,12-dimethoxy-2,8,10,14-tetramethylpentadeca-2,4,8-trienoate

: 1402167-46-7
C₄₈H₇₇NO₉Si

Guidance literature:: With sodium tetrahydroborate; sulfur; In tetrahydrofuran; at 65 ℃; for 2.5h;
DOI:10.1002/chem.201201600

Reference yield:

: 1118756-81-2
C₂₄H₄₀O₅

: 1402167-46-7
C₄₈H₇₇NO₉Si

Guidance literature:: Multi-step reaction with 13 steps

1: potassium hydride / tetrahydrofuran; mineral oil / 16 h / 0 - 20 °C

2: osmium(VIII) oxide; 4-methylmorpholine N-oxide / dichloromethane; water / 16 h / 20 °C

3: sodium periodate / water; acetone / 1 h / 20 °C

4: samarium diiodide / tetrahydrofuran / 1 h / -78 °C

5: Martins sulfurane / dichloromethane / 1 h / 0 °C

6: L-Selectride / tetrahydrofuran / 0.5 h / -78 °C

7: 1H-imidazole / N,N-dimethyl-formamide / 16 h

8: copper(II) nitrate / acetic anhydride / 2.25 h / 0 °C

9: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 12 h / 20 °C

10: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

11: potassium dihydrogenphosphate; 2-methyl-but-2-ene; sodium perchlorate / water; tert-butyl alcohol / 12 h / 20 °C

12: methanol; hexane; toluene / 0.5 h / 20 °C

13: sodium tetrahydroborate; sulfur / tetrahydrofuran / 2.5 h / 65 °C

With pyridine; 1H-imidazole; sodium tetrahydroborate; sodium periodate; potassium dihydrogenphosphate; osmium(VIII) oxide; samarium diiodide; 2-methyl-but-2-ene; Martins sulfurane; sodium perchlorate; potassium hydride; L-Selectride; sodium hydrogencarbonate; Dess-Martin periodane; copper(II) nitrate; pyridine hydrogenfluoride; sulfur; 4-methylmorpholine N-oxide; In tetrahydrofuran; methanol; hexane; dichloromethane; water; acetic anhydride; N,N-dimethyl-formamide; acetone; toluene; mineral oil; tert-butyl alcohol; 4: Reformatsky-type reaction;
DOI:10.1002/chem.201201600

Reference yield:

: 1402167-29-6
(S,2E,4Z)-methyl 7-(tert-butyldimethylsilyloxy)-6-hydroxy-2-methylhepta-2,4-dienoate

: 1402167-46-7
C₄₈H₇₇NO₉Si

Guidance literature:: Multi-step reaction with 17 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 2 h / -20 °C

2.1: diisobutylaluminium hydride / tetrahydrofuran; cyclohexane / 3 h / -78 - -20 °C

3.1: 1H-imidazole / dichloromethane / 0.25 h / -20 °C

4.1: camphor-10-sulfonic acid / methanol; dichloromethane / 2 h / 0 °C

5.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / acetonitrile / 3 h / 85 °C

6.1: isopropylmagnesium chloride / tetrahydrofuran / 0.5 h / -78 °C

6.2: 2 h / -78 °C

7.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 3 h / 20 °C

8.1: samarium diiodide / tetrahydrofuran / 1.5 h / -78 °C

9.1: Martins sulfurane / dichloromethane / 1 h / 0 °C

10.1: L-Selectride / tetrahydrofuran / 0.5 h / -78 °C

11.1: 1H-imidazole / N,N-dimethyl-formamide / 16 h

12.1: copper(II) nitrate / acetic anhydride / 2.25 h / 0 °C

13.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 12 h / 20 °C

14.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

15.1: potassium dihydrogenphosphate; 2-methyl-but-2-ene; sodium perchlorate / water; tert-butyl alcohol / 12 h / 20 °C

16.1: methanol; hexane; toluene / 0.5 h / 20 °C

17.1: sodium tetrahydroborate; sulfur / tetrahydrofuran / 2.5 h / 65 °C

With pyridine; 1H-imidazole; sodium tetrahydroborate; potassium dihydrogenphosphate; samarium diiodide; 2-methyl-but-2-ene; Martins sulfurane; camphor-10-sulfonic acid; sodium perchlorate; isopropylmagnesium chloride; L-Selectride; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; copper(II) nitrate; pyridine hydrogenfluoride; sulfur; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; hexane; dichloromethane; cyclohexane; water; acetic anhydride; N,N-dimethyl-formamide; toluene; acetonitrile; mineral oil; tert-butyl alcohol;
DOI:10.1002/chem.201201600