(η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III)

Base Information

• Chemical Name: (η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III)
• CAS No.: 313705-95-2
• Molecular Formula: C₁₈H₁₉ClCoNO₆S₃
• Molecular Weight: 535.996
• Mol file: 313705-95-2.mol

Synonyms:(η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III)

Chemical Property of (η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III)

There total 1 articles about (η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

(η5-cyclopentadienyl)(p-toluenesulfonylimido-kN-thio-kS-ethene-2-thiolato-kS)cobalt(III) → (η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III) (313705-95-2)

Guidance literature:

With HCl; In dichloromethane; to a soln. of complex in CH2Cl2 was added concd. HCl, the suspn. was stirred under Ar for 5 min; H2O was removed with MgSO4, the solvent was distilled under reduced pressure; elem. anal.;

DOI:10.1016/S0022-328X(00)00408-3

Reference yield:

(η5-cyclopentadienyl)(chloro)(p-toluenesulfonylimidothio-kS-ethene-2-thiolato-kS)cobalt(III) (313705-95-2) → (η5-cyclopentadienyl)(p-toluenesulfonylimido-kN-thio-kS-ethene-2-thiolato-kS)cobalt(III)

Guidance literature:

With pyridine; In dichloromethane; shaking a CH2Cl2-soln. with a small amounts of pyridine; evapd., detected by 1H-NMR spectra;

DOI:10.1016/S0022-328X(00)00408-3