(CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

Base Information

Chemical Name:(CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)
CAS No.:89828-40-0
Molecular Formula:C₃₄H₂₆Mo₂O₈P₂
Molecular Weight:816.403
Hs Code.:

(CO)4Mo(P(C<sub>6</sub>H<sub>5</sub>)2)2Mo(CO)3(C(OCH<sub>3</sub>)CH<sub>3</sub>)

Synonyms:(CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

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Chemical Property of (CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

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Technology Process of (CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

There total 3 articles about (CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: bis-μ-diphenylphosphido-octacarbonyldimolybdenum (Mo-Mo)

: 917-54-4
methyllithium

: 420-37-1
trimethoxonium tetrafluoroborate

: 89828-40-0
(CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

Guidance literature:: In tetrahydrofuran; nitromethane; formation of Li((CO)4Mo(μ-P(C6H5)2)2Mo(CO)3(C(O)CH3))*3C4H8O from Mo2(CO)8(μ-P(C6H5)2)2 and CH3Li in THF and freeing of the solvent; addn. of (CH3)3OBF4; addn. of nitromethane; stirring for a few minutes; removing of the solvent;; extraction with THF; filtration through activated alumina; evaporation of the solvent;;
DOI:10.1021/ja00246a018

Reference yield:

: 89828-34-2
2K⁽¹⁺⁾*{Mo₂(CO)8(P(C₆H₅)2)2}^(2-)*2C₄H₈O=K₂{Mo₂(CO)8(P(C₆H₅)2)2}*2C₄H₈O

: 420-37-1
trimethoxonium tetrafluoroborate

: bis-μ-diphenylphosphido-octacarbonyldimolybdenum (Mo-Mo)

: 89828-40-0
(CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

Guidance literature:: In nitromethane; addn. of CH3NO2 to a mixture of K2(Mo2(CO)8(μ-P(C6H5)2)2)*2THF (0.2 mmol) and (CH3)3OBF4 (0.4 mmol) with stirring; removing of solvent;; extraction with THF; filtration of the extract; concn.; detn. by 31P(1H) NMR spectroscopy; not isolated;;
DOI:10.1021/ja00246a018

Reference yield:

: 89828-36-4
Li⁽¹⁺⁾*Mo₂(P(C₆H₅)2)2(COCH₃)(CO)7^(1-) = Li[Mo₂(P(C₆H₅)2)2(COCH₃)(CO)7]

: 420-37-1
trimethoxonium tetrafluoroborate

: 89828-40-0
(CO)4Mo(P(C₆H₅)2)2Mo(CO)3(C(OCH₃)CH₃)

Guidance literature:: In nitromethane; Mo-complex was treated with 1 equiv of Me3OBF4 in MeNO2 for 10 min under N2; product was obtained in poor yield; solvent was removed, product was extd. into THF; formulated from (1)H and (31)P NMR evidence;