Technology Process of C25H40O5Si
There total 11 articles about C25H40O5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C26H42O4Si;
With
ozone;
In
dichloromethane;
at -78 ℃;
With
oxygen; triphenylphosphine;
In
dichloromethane;
at -78 - 20 ℃;
DOI:10.1021/ol102925d
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 13 h / 20 °C
2.1: pyridinium p-toluenesulfonate / dichloromethane / 20 °C
3.1: 5% Pd(II)/C(eggshell); hydrogen / ethyl acetate / 20 °C
4.1: CSA / dichloromethane / 20 °C
4.2: 0.75 h / 0 °C
5.1: diisobutylaluminium hydride / hexane; dichloromethane / 0 - 20 °C
6.1: dmap; triethylamine / dichloromethane / 16 h / 0 °C
7.1: dichloromethane / 0.5 h
8.1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C
9.1: ozone / dichloromethane / -78 °C
9.2: -78 - 20 °C
With
dmap; lithium aluminium tetrahydride; 5% Pd(II)/C(eggshell); tetrabutyl ammonium fluoride; hydrogen; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; ozone; acetic acid; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane; ethyl acetate;
DOI:10.1021/ol102925d
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: CSA / dichloromethane / 20 °C
1.2: 0.75 h / 0 °C
2.1: diisobutylaluminium hydride / hexane; dichloromethane / 0 - 20 °C
3.1: dmap; triethylamine / dichloromethane / 16 h / 0 °C
4.1: dichloromethane / 0.5 h
5.1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C
6.1: ozone / dichloromethane / -78 °C
6.2: -78 - 20 °C
With
dmap; lithium aluminium tetrahydride; diisobutylaluminium hydride; ozone; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ol102925d
