(4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol

Base Information

Chemical Name:(4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol
CAS No.:116697-28-0
Molecular Formula:C₂₉H₃₆O₄Si
Molecular Weight:476.688
Hs Code.:

Synonyms:(4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol

Suppliers and Price of (4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol

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Technology Process of (4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol

There total 15 articles about (4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 116697-27-9
((2S,4R)-2-Benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-tert-butyl-diphenyl-silane

: 116697-28-0
(4R,6S)-6-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-ol

Guidance literature:: With water; acetic acid; In tetrahydrofuran; at 75 ℃;
DOI:10.1016/S0040-4039(00)86112-2

Reference yield: 52.0%

: 94371-09-2,112996-07-3,112996-08-4,116697-27-9
methyl 2,4-dideoxy-3-O-diphenyl-t-butylsilyl-6-O-benzyl-α- and β-D-threo-hexopyranosides

: 88096-38-2,88096-39-3,116697-28-0
2,4-dideoxy-3-O-diphenyl-t-butylsilyl-6-O-benzyl-α- and β-D-threo-hexopyranoses

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; for 5h; Heating;

Reference yield:

: 88096-28-0
1,6-anhydro-2,4-dideoxy-3-O-allyl-β-D-threo-hexopyranose

: 88096-38-2,88096-39-3,116697-28-0
2,4-dideoxy-3-O-diphenyl-t-butylsilyl-6-O-benzyl-α- and β-D-threo-hexopyranoses

Guidance literature:: Multi-step reaction with 5 steps

1: Amberlite IR 118

2: NaH

3: Rh(PPh₃)3Cl

4: CH₃OH, Amberlite IR 118

5: 1.) KH, 2.) formic acid

With methanol; Wilkinson's catalyst; formic acid; Amberlite IR 118; potassium hydride; sodium hydride;
DOI:10.1039/c39830000829