[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

Base Information

Chemical Name:[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]
CAS No.:738585-39-2
Molecular Formula:C₂₄H₁₈NiPS₃Se*C₃₆H₃₀NP₂
Molecular Weight:1109.82
Hs Code.:

[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C<sub>6</sub>H<sub>4</sub>S)2(o-C<sub>6</sub>H<sub>4</sub>SH))]

Synonyms:[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

Suppliers and Price of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

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Chemical Property of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

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Technology Process of [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

There total 2 articles about [bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 186509-80-8
[PPN][SePh]

: 881734-67-4
[Ni(II)(PPh₃)(P(o-C₆H₄S)2(o-C₆H₄SH))]

: 738585-39-2
[PPN][Ni(II)(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

Guidance literature:: In tetrahydrofuran; under N2 atm. soln. Ni complex and (PPN)(SePh) in THF was stirred overnight at room temp.; Et2O was added;
DOI:10.1021/ic051924w

Reference yield:

: 119327-19-4
tris(2-mercaptophenyl)phosphine

: 738585-39-2
[PPN][Ni(II)(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: tetrahydrofuran

In tetrahydrofuran;
DOI:10.1021/ic051924w

Reference yield: 90.0%

: 738585-39-2
[bis(triphenylphosphoranylidene)ammonium][Ni(SePh)(P(o-C₆H₄S)2(o-C₆H₄SH))]

: [bis(triphenylphosphoranylidene)ammonium][Ni₂(P(o-C₆H₄S)3)2]

Guidance literature:: With Et₃N; In tetrahydrofuran; acetonitrile; under N2; Et3N (30 equiv.) added to THF-MeCN soln. of Ni complex at 5°C; stirred at 5°C for 10 min; layered with Et2O; sealed; crystd. at -15°C for 1 wk; detd. by X-ray single-crystal diffraction;
DOI:10.1021/ja048568l