(Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene

Base Information

• Chemical Name: (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene
• CAS No.: 770715-36-1
• Molecular Formula: C₁₇H₂₇BO₂Sn
• Molecular Weight: 392.921
• Mol file: 770715-36-1.mol

Synonyms:(Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene

Chemical Property of (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene

There total 1 articles about (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2,3-dimethyl-2,3-butane diol (76-09-5) + Bis(diethylamino)(trimethylstannyl)boran (79812-14-9) + phenylacetylene (536-74-3) → (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene (770715-36-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In benzene; benzene, 60°C; pinacol, room temp.;

DOI:10.1021/ja046429y

Reference yield: 45.0%

propargyl bromide (106-96-7) + (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene (770715-36-1) → (E)-4-phenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)penta-1,2,4-triene

Guidance literature:

With copper(l) iodide; trans benzyl(chloro)bis(triphenylphosphine)palladium(II); In N,N-dimethyl-formamide; at 20 - 35 ℃; for 19h;

DOI:10.1021/ja046429y

Reference yield: 11.0%

3-chloro-but-1-yne (21020-24-6) + (Z)-1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-(trimethylstannyl)ethene (770715-36-1) → (E)-2-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexa-1,3,4-triene

Guidance literature:

With copper(l) iodide; trans benzyl(chloro)bis(triphenylphosphine)palladium(II); In N,N-dimethyl-formamide; at 20 - 35 ℃; for 19h;

DOI:10.1021/ja046429y

upstream raw materials:

2,3-dimethyl-2,3-butane diol

Bis(diethylamino)(trimethylstannyl)boran

phenylacetylene