S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate

Base Information

• Chemical Name: S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate
• CAS No.: 1611489-73-6
• Molecular Formula: C₁₈H₂₄O₃S₂
• Molecular Weight: 352.519
• Mol file: 1611489-73-6.mol

Synonyms:S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate

Chemical Property of S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate

There total 6 articles about S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Geraniol (106-24-1) → S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate (1611489-73-6)

Guidance literature:

Multi-step reaction with 5 steps

1: phosphorus tribromide / dichloromethane / 1 h / 0 °C

2: N,N-dimethyl-formamide / 2 h / 20 °C

3: selenium(IV) oxide; tert.-butylhydroperoxide; 4-hydroxy-benzoic acid / dichloromethane / 24 h / 0 °C / Inert atmosphere; Darkness

4: carbon tetrabromide; triphenylphosphine / dichloromethane / 2 h / 20 °C

5: N,N-dimethyl-formamide / 1 h / 20 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; carbon tetrabromide; phosphorus tribromide; triphenylphosphine; 4-hydroxy-benzoic acid; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.3390/molecules19011120

Reference yield:

trans-geranyl bromide (6138-90-5) → S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate (1611489-73-6)

Guidance literature:

Multi-step reaction with 4 steps

1: N,N-dimethyl-formamide / 2 h / 20 °C

2: selenium(IV) oxide; tert.-butylhydroperoxide; 4-hydroxy-benzoic acid / dichloromethane / 24 h / 0 °C / Inert atmosphere; Darkness

3: carbon tetrabromide; triphenylphosphine / dichloromethane / 2 h / 20 °C

4: N,N-dimethyl-formamide / 1 h / 20 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; carbon tetrabromide; triphenylphosphine; 4-hydroxy-benzoic acid; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.3390/molecules19011120

Reference yield:

3,7-dimethyl-1-(phenylsulfonyl)-8-hydroxy-2(E),6(E)-octadiene (95763-61-4) → S-(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-yl ethanethioate (1611489-73-6)

Guidance literature:

Multi-step reaction with 2 steps

1: carbon tetrabromide; triphenylphosphine / dichloromethane / 2 h / 20 °C

2: N,N-dimethyl-formamide / 1 h / 20 °C

With carbon tetrabromide; triphenylphosphine; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.3390/molecules19011120

upstream raw materials:

trans-geranyl bromide

geranyl phenyl sulfone

(2E,6E)-2,6-dimethyl-8-(phenylsulfonyl)octa-2,6-dien-1-al

3,7-dimethyl-1-(phenylsulfonyl)-8-hydroxy-2(E),6(E)-octadiene

Downstream raw materials:

(2Z,6E,10E)-12-(acetylthio)-7,11-dimethyl-5-(phenylsulfonyl)dodeca-2,6,10-trien-1-yl 2,3,4-tri-Oacetyl-6-deoxy-α-D-heptomannopyranosiduronic acid

(2Z,6E,10E)-12-(acetylthio)-7,11-dimethyl-5-(phenylsulfonyl)dodeca-2,6,10-trien-1-yl 2,3,4-tri-Oacetyl-6-deoxy-6-azido-α-D-mannopyranoside