methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

Base Information

Chemical Name:methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose
CAS No.:101155-66-2
Molecular Formula:C₂₈H₃₀O₄
Molecular Weight:430.544
Hs Code.:

Synonyms:methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

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Chemical Property of methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

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Technology Process of methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

There total 7 articles about methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 66176-68-9
methyl 2,3-dideoxy-2-C-methyl-6-O-trityl-α-D-glycero-hex-2-enopyranosid-4-ulose

: 101155-66-2
methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

Guidance literature:: DOI:10.1246/cl.1985.965

Reference yield: 72.0%

: 917-54-4
methyllithium

: 66176-68-9
methyl 2,3-dideoxy-2-C-methyl-6-O-trityl-α-D-glycero-hex-2-enopyranosid-4-ulose

: 101155-66-2
methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

: methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-β-L-glycero-hexopyranosid-4-ulose

Guidance literature:: With copper(l) cyanide; In diethyl ether; at -78 ℃; for 4h;
DOI:10.1246/bcsj.60.1433

Reference yield:

: 101155-69-5
methyl 2,3-dideoxy-6-o-trityl-α-D-glycero-hex-2-enopyranosid-4-ulose

: 101155-66-2
methyl 2,3-dideoxy-2,2-di-C-methyl-6-O-trityl-α-D-glycero-hexopyranosid-4-ulose

Guidance literature:: Multi-step reaction with 4 steps

1: copper(I) cyanide, trimethylamine, hexamethylphosphoric triamide / -78 degC, 4 h; 0 deg.C, 1 h

2: 62 percent / p-benzoquinone, palladium(II) acetate / acetonitrile / 6 h / 50 °C

3: copper(I) cyanide, trimethylamine, hexamethylphosphoric triamide / -78 deg C, 4 h; 0 deg C, 1 h

4: 1.) disiamylborane, sodium hydroxide, 30 percent hydrogen peroxide; 2.) pyridine / 1.) THF, rt, 8 h; 45 deg C, 30 min

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; dihydrogen peroxide; palladium diacetate; copper(l) cyanide; bis-(1,2-dimethylpropyl)borane; p-benzoquinone; trimethylamine; In acetonitrile;
DOI:10.1246/bcsj.60.1433