[(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate

Base Information

Chemical Name:[(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate
CAS No.:184219-45-2
Molecular Formula:CF₃O₃S*C₂₉H₃₆CuN₄
Molecular Weight:653.248
Hs Code.:

Synonyms:[(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate

Chemical Property:

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Technology Process of [(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate

There total 2 articles about [(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 58452-28-1
tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate

: 125262-43-3
N,N',N''-tribenzyl-1,4,7-triazacyclononane

: 184219-45-2
[(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate

Guidance literature:: In tetrahydrofuran; stirring (10 min), addn. of Et2O, filtration; recrystn. (THF/ether or CH2Cl2/ether); elem. anal.;
DOI:10.1021/ja962305c

Reference yield:

: [(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(II) chloride]

: 35895-70-6
tetrabutylammonium trifluoromethylsulfonate

: 75-05-8,26809-02-9
acetonitrile

: 184219-45-2
[(1,4,7-tribenzyl-1,4,7-triazacyclononane)copper(I)(acetonitrile)] triflate

Guidance literature:: With 2,4,6-trimethylphenol; triethylamine; In dichloromethane; byproducts: stilbenequinone; under argon, at -5°C; layering the soln. with acetonitrile containing tetrabulylammonium triflate strictly in the absence of oxygen;
DOI:10.1246/cl.2000.1318